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(Dimethyl-formamide-?O){4,4',6,6'-tetra-bromo-2,2'-[o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-?O,N,N',O'}copper(II) dimethyl-formamide solvate.

ABSTRACT: In the title compound, [Cu(C(20)H(10)Br(4)N(2)O(2))(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) ion is coordinated by two N atoms and two O atoms from a tetra-dentate Schiff base ligand and the O atom of one dimethyl-formamide ligand in an almost square-pyramidal geometry. The uncoordinated dimethyl-formamide solvent mol-ecule is disordered over two sets of positions with occupancies of 0.741?(4) and 0.259?(4). The crystal packing is stabilized by C-H?O inter-actions.

SUBMITTER: Wu Y

PROVIDER: S-EPMC2969304 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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(Dimethyl-formamide-κO){4,4',6,6'-tetra-bromo-2,2'-[o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}copper(II) dimethyl-formamide solvate.

Wu Yu Y Xie Bin B Zou Li-Ke LK Wu Wei-Ping WP Lu Lu L

Acta crystallographica. Section E, Structure reports online 20090610 Pt 7

In the title compound, [Cu(C(20)H(10)Br(4)N(2)O(2))(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) ion is coordinated by two N atoms and two O atoms from a tetra-dentate Schiff base ligand and the O atom of one dimethyl-formamide ligand in an almost square-pyramidal geometry. The uncoordinated dimethyl-formamide solvent mol-ecule is disordered over two sets of positions with occupancies of 0.741 (4) and 0.259 (4). The crystal packing is stabilized by C-H⋯O inter-actions. ...[more]

PMID: 21582693

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