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3-(9-Anthrylmethyl)-1-benzylperimi-dinium hexa-fluoro-phosphate.

ABSTRACT: In the title compound, C(33)H(25)N(2) (+)·PF(6) (-), the naphthalene ring system is twisted with respect to the anthracene and benzene rings, making dihedral angles of 72.40?(3) and 71.39?(4)°, respectively. The crystal structure is stabilized by intermolecular C-H?F hydrogen bonding. Four F atoms of the hexa-fluoro-phosphate anion are disordered over two sets of sites in a 0.645?(4):0.355?(4) ratio.

SUBMITTER: Wang GY

PROVIDER: S-EPMC2969606 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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3-(9-Anthrylmethyl)-1-benzylperimi-dinium hexa-fluoro-phosphate.

Wang Gui-Yu GY Zhang Shi-Lu SL Qin Da-Bin DB

Acta crystallographica. Section E, Structure reports online 20090514 Pt 6

In the title compound, C(33)H(25)N(2) (+)·PF(6) (-), the naphthalene ring system is twisted with respect to the anthracene and benzene rings, making dihedral angles of 72.40 (3) and 71.39 (4)°, respectively. The crystal structure is stabilized by intermolecular C-H⋯F hydrogen bonding. Four F atoms of the hexa-fluoro-phosphate anion are disordered over two sets of sites in a 0.645 (4):0.355 (4) ratio. ...[more]

PMID: 21583136

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