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Redetermination of tetra-kis(N,N-diethyl-dithio-carbamato)tin(IV).

ABSTRACT: The crystal structure of the title compound, [Sn(C(5)H(10)NS(2))(4)], was originally determined by Harreld & Schlemper [Acta Cryst. (1971), B27, 1964-1969] using intensity data estimated from Weissenberg films. In comparison with the previous refinement, the current redetermination reveals anisotropic displacement parameters for all non-H atoms, localization of the H atoms, and higher precision of lattice parameters and inter-atomic distances. The complex features a distorted S(6) octa-hedral coordination geometry for tin and a cis disposition of the monodentate dithio-carbamate ligands.

SUBMITTER: Okio CK

PROVIDER: S-EPMC2969649 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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Redetermination of tetra-kis(N,N-diethyl-dithio-carbamato)tin(IV).

Okio Coco K Y A CK Speziali Nivaldo L NL

Acta crystallographica. Section E, Structure reports online 20090523 Pt 6

The crystal structure of the title compound, [Sn(C(5)H(10)NS(2))(4)], was originally determined by Harreld & Schlemper [Acta Cryst. (1971), B27, 1964-1969] using intensity data estimated from Weissenberg films. In comparison with the previous refinement, the current redetermination reveals anisotropic displacement parameters for all non-H atoms, localization of the H atoms, and higher precision of lattice parameters and inter-atomic distances. The complex features a distorted S(6) octa-hedral co ...[more]

PMID: 21583036

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