Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

1,2-Dibenzoyl-hydrazine-dimethyl-formamide (3/1).

ABSTRACT: The title compound, 3C(14)H(12)N(2)O(2)·C(3)H(7)NO, was synthesized by reaction of benzoyl chloride with hydrazine hydrate under microwave irradition. The asymmetric unit comprises three 1,2-dibenzoyl-hydrazine mol-ecules and one dimethyl-formamide mol-ecule. The 1,2-dibenzoyl-hydrazine mol-ecules are linked by pairs of N-H?O hydrogen bonds into chains propagating along [010].

SUBMITTER: He QP

PROVIDER: S-EPMC2969677 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

1,2-Dibenzoyl-hydrazine-dimethyl-formamide (3/1).

He Qing-Peng QP Li Hong-Gang HG Wang Guang-Bo GB Fu Feng-Lian FL Liu Ming-Shi MS

Acta crystallographica. Section E, Structure reports online 20090514 Pt 6

The title compound, 3C(14)H(12)N(2)O(2)·C(3)H(7)NO, was synthesized by reaction of benzoyl chloride with hydrazine hydrate under microwave irradition. The asymmetric unit comprises three 1,2-dibenzoyl-hydrazine mol-ecules and one dimethyl-formamide mol-ecule. The 1,2-dibenzoyl-hydrazine mol-ecules are linked by pairs of N-H⋯O hydrogen bonds into chains propagating along [010]. ...[more]

PMID: 21583131

Similar Datasets

2-Isonicotinoyl-N-phenyl-hydrazine-carbothio-amide dimethyl-formamide hemisolvate.

Project description:The title compound, C(13)H(12)N(4)OS·0.5C(3)H(7)NO, contains four hydrazine mol-ecules and two solvent mol-ecules in the asymmetric unit. The dihedral angles between the pyridine and phenyl rings in the hydrazine mol-ecules are 67.51 (16), 68.28 (16), 81.36 (15) and 83.32 (15)°. In the crystal, the mol-ecules are linked by N-H⋯N, N-H⋯O and N-H⋯S hydrogen bonds.

| S-EPMC3089371 | biostudies-literature

Dimethyl hydrazine-1,2-dicarboxyl-ate-triphenyl-phosphine oxide (1/1).

Project description:In the crystal structure of the title compound, C(4)H(8)N(2)O(4)·C(18)H(15)OP, two triphenyl-phosphine oxide mol-ecules and two dimethyl hydrazine-1,2-dicarboxyl-ate mol-ecules are connected via N-H⋯O hydrogen bonds of moderate strength and are related via a twofold rotational axis. Weak C(ar)-H⋯ O contacts strengthen the crystal structure.

| S-EPMC3151943 | biostudies-literature

[?-1,2-Bis(diphenyl-phosphan-yl)-1,2-dimethyl-hydrazine-?P:P']bis-[chlorido-gold(I)].

Project description:The title compound, [Au(2)Cl(2)(C(26)H(26)N(2)P(2))], is formed from a bidentate phosphine ligand complexed to two linearly coordinated gold(I) atoms. The gold(I) atoms are 3.4873?(7)?Å apart. The mol-ecule exhibits a crystallographic twofold rotation axis.

| S-EPMC3050310 | biostudies-literature

2,2'-(Diselane-1,2-di-yl)dinicotinamide N,N'-dimethyl-formamide disolvate.

Project description:The asymmetric unit of the title compound, C(12)H(10)N(4)O(2)Se(2)·2C(3)H(7)NO, contains two solvent mol-ecules and two half mol-ecules of the dinicotinamide, each of which sits on a center of symmetry passing through the middle of the Se-Se bond. In each mol-ecule, the two pyridyl groups and diseleno group are approximately coplanar (r.m.s. deviations from planarity for all non-H atoms = 0.011 and 0.008?Å in the two mol-ecules). Inter-molecular N-H?O hydrogen bonds stablilize the crystal packing.

| S-EPMC2979017 | biostudies-literature

(E)-5,5'-(Diazene-1,2-di-yl)diisophthalic acid N,N-dimethyl-formamide disolvate.

Project description:The title compound, C(16)H(10)N(2)O(8)·2C(3)H(7)NO, was synthesized by the reductive condensation reaction of 5-nitro-isophthalic acid in the presence of NaOH. The tetra-acid mol-ecule, which has a crystallographically imposed centre of symmetry, adopts an E configuration with respect to the azo group. In the crystal packing, mol-ecules are linked through inter-molecular O-H⋯O and C-H⋯O hydrogen-bonding inter-actions, forming chains propagating in [20].

| S-EPMC2959636 | biostudies-literature

3,5-Dibenzoyl-2,6-dimethyl-1-pentyl-4-pyridone.

Project description:In the crystal structure of the title compound, C(26)H(27)NO(3), a one-dimensional network of C-H?O hydrogen bonds and ?-ring inter-actions is responsible for crystal stabilization. Inter-molecular hydrogen bonds and C-H? ? inter-actions produce R(2) (2)(10), R(4) (4)(27) and R(4) (4)(29) rings.

| S-EPMC2968478 | biostudies-literature

1,2-Bis(diphenyl-phosphino)-1,2-diethyl-hydrazine.

Project description:The title compound, C(28)H(30)N(2)P(2), adopts a well documented and studied gauche conformation around the hydrazine bond. Bond lengths and angles are in the typical ranges expected for P-N and P-C bonds. A normal hydrazine N-N bond length of 1.426?(3)?Å is observed.

| S-EPMC2979499 | biostudies-literature

{6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolato}nickel(II) dimethyl-formamide monosolvate.

Project description:In the title compound, [Ni(C(18)H(18)N(2)O(4))]·C(3)H(7)NO, the central Ni(II) atom is in a square-planar O(2)N(2) coordination environment. The planar Ni-salen moieties (r.m.s. deviation for the plane through the conjugated part of the Ni-salen group = 0.07 Å) form parallel stacks in the a-axis direction, with alternating Ni⋯Ni separations of 3.5339 (7) and 3.6165 (7) Å. In the crystal, there are weak inter-molecular C-H⋯O inter-actions involving the dimethyl-formamide O and phenolate O atoms.

| S-EPMC3051997 | biostudies-literature

{?-1,2-Bis[bis(4-meth-oxy-phen-yl)phosphan-yl]-1,2-dimethyl-hydrazine-?P:P'}bis-[chloridogold(I)] tetra-hydro-furan disolvate.

Project description:The title compound, [Au(2)Cl(2)(C(30)H(34)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two almost linearly coordinated gold(I) atoms [P-Au-Cl = 175.68?(3)?Å]. The nuclei are 3.122?(2)?Å apart. The mol-ecule exhibits a twofold rotation axis.

| S-EPMC3212261 | biostudies-literature

catena-Poly[[[bis-(N,N-dimethyl-formamide)iron(II)]-{μ-2,2'-bis-(diphenyl-phosphino-yl)-N,N'-[(1R,2R)-cyclo-hexane-1,2-di-yl]dibenzamide}] bis-(perchlorate) N,N-dimethyl-formamide disolvate].

Project description:The title extended solid coordination compound, {[Fe(C(44)H(40)N(2)O(4)P(2))(C(3)H(7)NO)(2)](ClO(4))(2)·2C(3)H(7)NO}(n), was crystallized un-ex-pectedly from the reaction mixture containing the Trost ligand (1R,2R)-(+)-1,2-diamino-cyclo-hexane-N,N'-bis-(2'-di-phenyl-phosphinobenzo-yl) and Fe(ClO(4))(2)·6H(2)O in a 1:1 ratio in dimethyl-formamide (DMF) under reflux conditions. The polymeric complex is characterized by Fe(II) metal centers that are coordinated by two oxidized Trost ligands, each coordinated in a bidentate fashion in a square plane, along with two DMF mol-ecules above and below the plane [average Fe-O(DMF) = 2.086 (4) Å], forming an overall pseudo-octa-hedral geometry. The Trost ligand binds adjacent Fe(II) centers, each Fe(II) being bound through the O atom of one of the phosphine oxides [average Fe-O(PPh2) = 2.115 (4) Å] and the carbonyl O atom of the adjacent amide [average Fe-O(amide) = 2.192 (3) Å]. Disorder is observed in the co-solvated solvent: there are two DMF mol-ecules per Fe(II) centre, which were modeled as one DMF mol-ecule with complete occupancy and the other being modeled in two positions with equal occupancy. Disorder was also observed with one of the perchlorate anions, which was modeled in two positions with 0.75:0.25 occupancy.

| S-EPMC2971940 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data