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2,2'-(Hexane-1,6-di-yl)diisoquinolinium tetra-chloridozincate(II).

ABSTRACT: The asymmetric unit of the title compound, (C(24)H(26)N(2))[ZnCl(4)], consists of two 2,2'-(hexane-1,6-di-yl)diisoquinolinium cations and two [ZnCl(4)](2-) complex anions. The [ZnCl(4)](2-) anions have a distorted tetra-hedral geometry. The dihedral angles between the isoquinoline rings of the two cations are nearly equal [16.1?(2) and 16.3?(2)°]. In the crystal structure, the ordered linear formation is aggregated by weak inter-molecular ?-? stacking inter-actions between neighboring isoquinoline pyridine rings with a centroid-centroid distance of 3.779?(4)?Å.

SUBMITTER: Ma PH

PROVIDER: S-EPMC2969707 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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2,2'-(Hexane-1,6-di-yl)diisoquinolinium tetra-chloridozincate(II).

Ma Pei-Hua PH Fan Zhi-Fang ZF Zhang Yun-Qian YQ Xiao Xin X Xue Sai-Feng SF

Acta crystallographica. Section E, Structure reports online 20090520 Pt 6

The asymmetric unit of the title compound, (C(24)H(26)N(2))[ZnCl(4)], consists of two 2,2'-(hexane-1,6-di-yl)diisoquinolinium cations and two [ZnCl(4)](2-) complex anions. The [ZnCl(4)](2-) anions have a distorted tetra-hedral geometry. The dihedral angles between the isoquinoline rings of the two cations are nearly equal [16.1 (2) and 16.3 (2)°]. In the crystal structure, the ordered linear formation is aggregated by weak inter-molecular π-π stacking inter-actions between neighboring isoquinoli ...[more]

PMID: 21583019

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