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Trans-Diaqua-bis[(E)-3-(dimethyl-amino)-1-(2-pyrid-yl)prop-2-en-1-one-?N,O]cobalt(II) dinitrate dihydrate.

ABSTRACT: In the title compound, [Co(C(10)H(12)N(2)O)(2)(H(2)O)(2)](NO(3))(2)·2H(2)O, the Co(II) ion, located on an inversion center, is trans-coordinated by two N,O-bidentate chelating (E)-3-(dimethyl-amino)-1-(2-pyrid-yl)prop-2-en-1-one ligands and by two water mol-ecules in a slightly distorted octa-hedral geometry. Inter-molecular O-H?O hydrogen bonds link the cations, anions and water mol-ecules into layers parallel to the ac plane. The crystal packing also exhibits weak inter-molecular C-H?O hydrogen bonds.

SUBMITTER: Bi JH

PROVIDER: S-EPMC2969776 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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trans-Diaqua-bis[(E)-3-(dimethyl-amino)-1-(2-pyrid-yl)prop-2-en-1-one-κN,O]cobalt(II) dinitrate dihydrate.

Bi Jian-Hong JH

Acta crystallographica. Section E, Structure reports online 20090514 Pt 6

In the title compound, [Co(C(10)H(12)N(2)O)(2)(H(2)O)(2)](NO(3))(2)·2H(2)O, the Co(II) ion, located on an inversion center, is trans-coordinated by two N,O-bidentate chelating (E)-3-(dimethyl-amino)-1-(2-pyrid-yl)prop-2-en-1-one ligands and by two water mol-ecules in a slightly distorted octa-hedral geometry. Inter-molecular O-H⋯O hydrogen bonds link the cations, anions and water mol-ecules into layers parallel to the ac plane. The crystal packing also exhibits weak inter-molecular C-H⋯O hydroge ...[more]

PMID: 21583001

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