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[N'-(3-Meth-oxy-2-oxidobenzyl-idene)nicotinohydrazidato]diphenyl-tin(IV).

ABSTRACT: The asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(14)H(11)N(3)O(3))], contains two crystallographically independent mol-ecules that differ predominantly in the torsion of the phenyl rings. In both mol-ecules, the Sn(IV) ion is in a distored trigonal-bipyramidal geometry. The Sn-O distances are in the range 2.055 (2)-2.143 (2) Å.

SUBMITTER: Gao Z

PROVIDER: S-EPMC2969951 | biostudies-literature |

REPOSITORIES: biostudies-literature

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[N-(3-Meth-oxy-2-oxidobenzyl-idene-?O)alaninato-?N,O]diphenyl-tin(IV).

Project description:The Sn atom of the title compound, [Sn(C(6)H(5))(2)(C(11)H(11)NO(4))], adopts a distorted SnNC(2)O(2) trigonal-bipyramidal geometry with the O atoms in the axial positions. The metal atom forms five- and six-membered chelate rings with the O,N,O'-tridentate ligand.

| S-EPMC2968303 | biostudies-literature

[N'-(3-Meth-oxy-2-oxidobenzyl-idene)nicotinohydrazidato]dimethyl-tin(IV).

Project description:In the title complex, [Sn(CH(3))(2)(C(14)H(11)N(3)O(3))], the Sn atom is in a distorted trigonal-bipyramidal coordination, with Sn-O distances of 2.138?(2) and 2.176?(2)?Å. The dihedral angles between the two chelated benzene rings and the O-Sn-N group are 71.73?(9) and 83.30?(9)°.

| S-EPMC2970494 | biostudies-literature

[4-Chloro-N'-(3-meth-oxy-2-oxidobenzyl-idene)benzohydrazidato]dimethyl-tin(IV).

Project description:In the title mol-ecule, [Sn(CH(3))(2)(C(15)H(11)ClN(2)O(3))], the two benzene rings form a dihedral angle of 6.37?(2)°. The Sn atom is coordinated by one N [Sn-N = 2.187?(3)?Å], two O [Sn-O = 2.123?(3) and 2.174?(3)?Å] and two C [Sn-C = 2.096?(4) and 2.101?(4)?Å] atoms in a distorted trigonal-bipyramidal geometry. The crystal packing exhibits weak inter-molecular C-H?O hydrogen bonds, which link the mol-ecules into centrosymmetric dimers with an Sn?Sn separation of 4.330?(6)?Å, and ?-? inter-actions [centroid-centroid distance of 3.690?(5)?Å between the benzene rings of neighbouring mol-ecules].

| S-EPMC2967882 | biostudies-other

Dieth-yl[N-(3-meth-oxy-2-oxidobenzyl-idene)-N'-(oxidomethyl-ene)hydrazine-κO,N,O']tin(IV).

Project description:In the mol-ecule of the title compound, [Sn(C(2)H(5))(2)(C(9)H(8)N(2)O(3))], the Sn atom is five-coordinated in a distorted trigonal-bipyramidal configuration by two O and one N atoms of the tridentate Schiff base ligand in the equatorial plane, and by two C atoms of ethyl groups in the axial positions. In the crystal structure, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers.

| S-EPMC2961818 | biostudies-literature

(2,2'-Bipyridine-κN,N'){[(3-meth-oxy-2-oxidobenzyl-idene-κO)hydrazono]methano-lato-κN,O}dimethyl-tin(IV).

Project description:In the crystal structure of the title compound, [Sn(CH(3))(2)(C(9)H(8)N(2)O(3))(C(10)H(8)N(2))], the Sn atom exhibits a penta-gonal bipyramidal coordination geometry defined by two C, three N and two O atoms. The bond distances for Sn-C, Sn-N and Sn-O are in the ranges 2.097 (3)-2.098 (3), 2.298 (2)-2.623 (2) and 2.157 (2)-2.266 (2) Å, respectively. The mol-ecular structure of the monomeric compound is stabilized by three intra-molecular C-H⋯O hydrogen bonds, all involving bipyridine C-H groups.

| S-EPMC2961040 | biostudies-literature

[N'-(5-Chloro-2-oxidobenzyl-idene-?O)-3-hydr-oxy-2-naphthohydrazidato-?N',O]diphenyl-tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(18)H(11)ClN(2)O(3))], is O,N,O'-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C(2)SnNO(2) trigonal-bipyramidal geometry [C-Sn-C = 125.7?(2)°]. The two phenyl rings are oriented at a dihedral angle of 55.2?(3)°. Intra-molecular O-H?N hydrogen bonding is present in the crystal structure.

| S-EPMC2971880 | biostudies-other

[N'-(5-Bromo-2-oxidobenzyl-idene-?O)-3-hydr-oxy-2-naphthohydrazidato-?N',O]dibutyl-tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(C(4)H(9))(2)(C(18)H(11)BrN(2)O(3))], shows a distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination. One of the butyl chains is disordered over two sites in a 0.60?(1):0.40?(1) ratio.

| S-EPMC2977471 | biostudies-literature

[N'-(5-Chloro-2-oxidobenzyl-idene-?O)-3-hydr-oxy-2-naphthohydrazidato-?N',O]dimethyl-tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(18)H(11)ClN(2)O(3))], shows a trans-C(2)NO(2)Sn trigonal-bipyramidal coordin-ation; the axial O-Sn-O angle is 155.22?(5)°. The tridentate N'-(5-chloro-2-oxidobenzyl-idene)-3-hydr-oxy-2-naphthohydrazidate dianion is stabilized by an intra-molecular O-H?N hydrogen bond.

| S-EPMC2969223 | biostudies-literature

[N'-(5-Bromo-2-oxidobenzyl-idene-?O)-3-hydr-oxy-2-naphthohydrazidato-?N',O]dimethyl-tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(18)H(11)BrN(2)O(3))], shows a distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination geometry, with an axial O-Sn-O angle of 155.27?(9)°. The presence of an intra-molecular O-H?N hydrogen bond between the amido N atom and hydr-oxy H atom in the Schiff base ligand helps to stabilize the overall mol-ecular structure.

| S-EPMC2979755 | biostudies-literature

[5-Chloro-2-hy-droxy-N'-(2-oxidobenzyl-idene)benzohydrazidato]dimethyl-tin(IV).

Project description:In the title compound, [Sn(CH(3))(2)(C(14)H(9)ClN(2)O(3))], the Sn(IV) ion is coordinated by one N and two O atoms from the tridentate 5-chloro-2-hy-droxy-N'-(2-oxidobenzyl-idene)benzohydrazidate (L) ligand and two methyl groups in a distorted trigonal-bipyramidal geometry. In the ligand, the hy-droxy group is involved in an intra-molecular O-H?N hydrogen bond and the two aromatic rings form a dihedral angle of 5.5?(1)°. In the crystal, weak inter-molecular C-H?O hydrogen bonds and ?-? inter-actions between the aromatic rings [centroid-centroid distance = 3.816?(3)?Å] link the mol-ecules into centrosymmetric dimers.

| S-EPMC3212120 | biostudies-literature

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