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Cis-Bis[1-allyl-3-(2-pyrid-yl-?N)thio-ureato-?S]palladium(II).

ABSTRACT: Yellow plate-like shaped crystals of the title compound, [Pd(C(9)H(10)N(3)S)(2)], were obtained by ligand-exchange reaction between palladium(II) acetyl-acetonate and the corresponding organic reagent at room temperature. The Pd(II) atom shows a slightly distorted square-planar coordination geometry consisting of two ligand mol-ecules in a cis conformation that bind in their thio-lic tautomeric form. Weak inter-molecular Pd?H inter-actions with Pd-H distances of 3.328?(2)?Å were observed in the crystal structure. The three-dimensional network of the crystal structure is realized by weak inter-molecular C-H?N, N-H?N and C-H?S hydrogen bonds.

SUBMITTER: Orysyk S

PROVIDER: S-EPMC2970023 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

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cis-Bis[1-allyl-3-(2-pyrid-yl-κN)thio-ureato-κS]palladium(II).

Orysyk Svitlana S Bon Volodimir V Pekhnyo Vasily V

Acta crystallographica. Section E, Structure reports online 20090812 Pt 9

Yellow plate-like shaped crystals of the title compound, [Pd(C(9)H(10)N(3)S)(2)], were obtained by ligand-exchange reaction between palladium(II) acetyl-acetonate and the corresponding organic reagent at room temperature. The Pd(II) atom shows a slightly distorted square-planar coordination geometry consisting of two ligand mol-ecules in a cis conformation that bind in their thio-lic tautomeric form. Weak inter-molecular Pd⋯H inter-actions with Pd-H distances of 3.328 (2) Å were observed in the ...[more]

PMID: 21577418

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