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Cis-Bis{1,1-dibenzyl-3-[(furan-2-yl)carbon-yl]thio-ureato-?O,S}nickel(II).

ABSTRACT: In the title compound, [Ni(C(20)H(17)N(2)O(2)S)(2)], the Ni(II) atom is coordinated by the S and O atoms of two 1,1-dibenzyl-3-[(furan-2-yl)carbon-yl]thio-ureate ligands in a distorted square-planar geometry. The two O and two S atoms are mutually cis to each other. The Ni-S and Ni-O bond lengths lie within the range of those found in related structures. The dihedral angle between the planes of the two chelating rings is 20.33?(6)°.

SUBMITTER: Perez H

PROVIDER: S-EPMC3100031 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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cis-Bis{1,1-dibenzyl-3-[(furan-2-yl)carbon-yl]thio-ureato-κO,S}nickel(II).

Pérez Hiram H da Silva Cecilia C P CC Plutín Ana M AM de Simone Carlos A CA Ellena Javier J

Acta crystallographica. Section E, Structure reports online 20110326 Pt 4

In the title compound, [Ni(C(20)H(17)N(2)O(2)S)(2)], the Ni(II) atom is coordinated by the S and O atoms of two 1,1-dibenzyl-3-[(furan-2-yl)carbon-yl]thio-ureate ligands in a distorted square-planar geometry. The two O and two S atoms are mutually cis to each other. The Ni-S and Ni-O bond lengths lie within the range of those found in related structures. The dihedral angle between the planes of the two chelating rings is 20.33 (6)°. ...[more]

PMID: 21754011

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