Browse
Submit Data
Databases
API
Help

Dataset Information

27 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

2-Meth-oxy-6-[(Z)-[(5-methyl-2-pyrid-yl)imino-meth-yl]phenol.

ABSTRACT: The title compound, C(14)H(14)N(2)O(2), was obtained by a condensation reaction between o-vanillin and 5-methyl-pyridin-2-amine. In the mol-ecule, the dihedral angle between the pyridine and benzene rings is 9.08?(13)°. An intra-molecular hydrogen bond involving the imine N atom and the hydroxyl group may influence the conformation of the mol-ecule. The crystal structure is stabilized by weak C-H?O hydrogen bonds.

SUBMITTER: Liu XY

PROVIDER: S-EPMC2970039 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

2-Meth-oxy-6-[(Z)-[(5-methyl-2-pyrid-yl)imino-meth-yl]phenol.

Liu Xin-Yu XY Fan Yu-Hua YH Bi Cai-Feng CF Wang Qiang Q Gao Yuan Y

Acta crystallographica. Section E, Structure reports online 20090815 Pt 9

The title compound, C(14)H(14)N(2)O(2), was obtained by a condensation reaction between o-vanillin and 5-methyl-pyridin-2-amine. In the mol-ecule, the dihedral angle between the pyridine and benzene rings is 9.08 (13)°. An intra-molecular hydrogen bond involving the imine N atom and the hydroxyl group may influence the conformation of the mol-ecule. The crystal structure is stabilized by weak C-H⋯O hydrogen bonds. ...[more]

PMID: 21577576

Similar Datasets

2-Eth-oxy-6-[(methyl-imino)-meth-yl]phenol.

Project description:In the title compound, C(10)H(13)NO(2), synthesized by the reaction of 2-hy-droxy-3-eth-oxy-benzaldehyde with methyl-amine, there is an an intra-molecular O-H?N hydrogen bond involving the hy-droxy substituent and the amino N atom. In the crystal, mol-ecules form inversion dimers connected by pairs of C-H?O hydrogen bonds.

| S-EPMC3006704 | biostudies-literature

Bis{2-meth-oxy-6-[(3-pyrid-yl)methyl-imino-meth-yl]phenolato}copper(II).

Project description:In the mononuclear title complex, [Cu(C(14)H(13)N(2)O(2))(2)], the Cu(II) atom lies on an inversion centre and adopts a square-planar coordination geometry. The dihedral angle formed by the pyridine and benzene rings is 74.61?(5)°. Intra-molecular C-H?O hydrogen bonds are present. The crystal structure is stabilized by weak aromatic ?-? stacking inter-actions involving neighbouring pyridine rings [centroid-centroid distance = 3.853?(2)?Å].

| S-EPMC2970154 | biostudies-literature

(E)-2-Meth-oxy-6-[(5-methyl-isoxazol-3-yl)imino-meth-yl]phenol.

Project description:In the title mol-ecule, C(12)H(12)N(2)O(3), the benzene and isoxazole rings form a dihedral angle of 5.9 (6)°. The hydr-oxy group is involved in an intra-molecular O-H⋯N hydrogen bond [O⋯N = 2.616 (5) Å], resulting in approximate planarity of the mol-ecular skeleton. In the crystal structure, mol-ecules related by translation along the c axis are stacked into columns, the shortest inter-molecular C⋯C distance being 3.298 (6) Å.

| S-EPMC2960214 | biostudies-literature

4-Meth-oxy-2-{(E)-[(thio-phen-2-yl)methyl-imino]-meth-yl}phenol.

Project description:The title Schiff base, C(13)H(13)NO(2)S, adopts the phenol-imine tautomeric form and reveals an intra-molecular O-H⋯N hydrogen bond involving the hy-droxy group and the imino N atom, forming an S(6) ring. The mol-ecule is highly twisted with respect to the central imine group, which is reflected in the dihedral angle of 67.83 (10)° formed by the thienyl and phenol rings. The crystal packing is characterized by weak C-H⋯O and C-H⋯π inter-actions.

| S-EPMC3435828 | biostudies-literature

2-Eth-oxy-6-[(3-methyl-pyridin-2-yl)-imino-meth-yl]phenol.

Project description:The title Schiff base compound, C(15)H(16)N(2)O(2), was prepared by the condensation reaction of equimolar quanti-ties of 3-eth-oxy-salicyl-aldehyde with 2-amino-3-methyl-pyridine in methanol. The dihedral angle between the benzene ring and the pyridine ring is 2.6?(2)° and an intra-molecular O-H?N hydrogen bond generates an S(6) ring.

| S-EPMC3089178 | biostudies-literature

2-[(4-Meth-oxy-benz-yl)imino-meth-yl]phenol.

Project description:In the title Schiff base compound, C(15)H(15)NO(2), prepared from 4-meth-oxy-benzyl-amine and salicyl-aldehyde, an intra-molecular O-H?N hydrogen bonds influences the mol-ecular conformation; the two aromatic rings form a dihedral angle of 73.5?(1)°. In the crystal, weak inter-molecular C-H?O inter-actions link the mol-ecules into chains propagating in [010].

| S-EPMC3011435 | biostudies-literature

2-{(E)-[(3-Iodo-4-methyl-phen-yl)imino]-meth-yl}-4-(trifluoro-meth-oxy)phenol.

Project description:The title compound, C(15)H(11)F(3)INO(2), adopts the enol-imine tautomeric form. The mol-ecule displays an E conformation with respect to the imine C=N double bond. The dihedral angle between the two benzene rings is 12.4 (2)°. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯N hydrogen bond, which generates an S(6) ring motif. The trifluoro-meth-oxy-phenyl group is disordered over two sites with an occupancy ratio of 0.621 (6):0.379 (6). The crystal structure features C-H⋯π inter-actions.

| S-EPMC3393956 | biostudies-literature

3-Meth-oxy-2-[(E)-(4-meth-oxy-phen-yl)imino-meth-yl]phenol.

Project description:The title compound, C(15)H(15)NO(3), adopts the enol-imine tautomeric form. The two rings are twisted with respect to each other, making a dihedral angle of 44.08 (5)°. The 3-methoxy-2-[(E)-(4-methoxyphenyl)-iminomethyl]phenol unit is almost planar, the largest deviation from the mean plane being 0.047 (2) Å. Such a planar conformation might be related to the occurrence of an intra-molecular O-H⋯N hydrogen bond. In the crystal, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into sheets parallel to (010). These sheets are inter-connected by weak C-H⋯π inter-actions.

| S-EPMC3051687 | biostudies-literature

Crystal structure of (E)-4-meth-oxy-2-{[(5-methyl-pyridin-2-yl)imino]-meth-yl}phenol.

Project description:The mol-ecule of the title Schiff base compound, C14H14N2O2, displays an E conformation with respect the imine C=N double bond. The mol-ecule is approximately planar, with the dihedral angle formed by the planes of the pyridine and benzene rings being 5.72 (6)°. There is an intra-molecular hydrogen bond involving the phenolic H and imine N atoms.

| S-EPMC4645057 | biostudies-literature

4-Meth-oxy-2-[(E)-(phenyl-imino)meth-yl]phenol.

Project description:In the mol-ecule of the title compound, C(14)H(13)NO(2), the two aromatic rings are oriented at a dihedral angle of 0.78?(20)°; with the exception of two methyl H atoms the mol-ecule is essentially planar. The intra-molecular O-H?N hydrogen bond results in the formation of a non-planar, six-membered ring, which adopts a flattened-boat conformation. In the crystal structure, inter-molecular C-H?O hydrogen bonds link the mol-ecules to form parallel networks. There is a C-H?? contact between the methyl group and the benzene ring. A ?-? contact between the benzene and phenyl rings [centroid-centroid distance = 4.681?(5)?Å] is also observed.

| S-EPMC2960573 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data