Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis{2-[2-(dimethyl-amino)ethyl-imino-meth-yl]-4,6-disulfanylphenolato}cobalt(II) monohydrate.

ABSTRACT: In the title hydrated complex, [Co(C(11)H(15)N(2)OS(2))(2)]·H(2)O, the Co(II) atom (site symmetry 2) is coordinated by two O,N,N'-tridentate Schiff base ligands, resulting in a very distorted cis-CoO(2)N(4) octa-hedral geometry for the metal ion. In the crystal, the water mol-ecule (O-atom site symmetry 2) inter-acts with nearby complex mol-ecules by way of bifurcated O-H?(O,S) hydrogen bonds.

SUBMITTER: Cai YJ

PROVIDER: S-EPMC2970116 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis{2-[2-(dimethyl-amino)ethyl-imino-meth-yl]-4,6-disulfanylphenolato}cobalt(II) monohydrate.

Cai Ying-Jie YJ Li Jin J Huang Peng P Zeng Qing-Fu QF

Acta crystallographica. Section E, Structure reports online 20090829 Pt 9

In the title hydrated complex, [Co(C(11)H(15)N(2)OS(2))(2)]·H(2)O, the Co(II) atom (site symmetry 2) is coordinated by two O,N,N'-tridentate Schiff base ligands, resulting in a very distorted cis-CoO(2)N(4) octa-hedral geometry for the metal ion. In the crystal, the water mol-ecule (O-atom site symmetry 2) inter-acts with nearby complex mol-ecules by way of bifurcated O-H⋯(O,S) hydrogen bonds. ...[more]

PMID: 21577479

Similar Datasets

Bis{2-[3-(dimethyl-amino)propyl-imino-meth-yl]-4,6-disulfanylphenolato}cobalt(II).

Project description:In the title mononuclear complex, [Co(C(12)H(17)N(2)OS(2))(2)], the Co(II) atom is four-coordinated by two N,O-bidentate Schiff base ligands, resulting in a slightly distorted trans-CoN(2)O(2) square-planar coordination.

| S-EPMC2970151 | biostudies-literature

Bis{2-[3-(dimethyl-amino)propyl-imino-meth-yl]-4,6-dihydro-seleno-phenolato}zinc(II).

Project description:In the title complex, [Zn(C(12)H(17)N(2)OSe(2))(2)], the Zn(II) ion is six-coordinated by two N,N',O-tridentate Schiff base ligands, resulting in a slightly distorted trans-ZnO(2)N(4) octa-hedral coordination for the metal ion.

| S-EPMC2969977 | biostudies-literature

[2,6-Bis(dimethyl-amino-meth-yl)phen-yl]selenium bromide monohydrate.

Project description:In the title hydrated molecular salt, C(12)H(19)N(2)Se(+)·Br(-)·H(2)O, the two independent bromide anions lie on a twofold rotation axis. Strong intra-molecular N→Se inter-actions [2.185 (3) and 2.181 (3) Å] are established by both N atoms of the organic group in the cation, in trans positions to each other, with an N-Se-N angle of 161.6 (1)°, resulting in a T-shaped (C,N,N')Se core. In the crystal, dimeric associations are formed by Br⋯Se [3.662 (2) Å] and Br⋯H inter-actions [2.56 (6) and 2.63 (7) Å] involving two bromide anions, two cations and two water mol-ecules.

| S-EPMC2983970 | biostudies-literature

Bis{2-[(E)-benzyl-imino-meth-yl]-4,6-dibromo-phenolato-?N,O}cobalt(II).

Project description:In the title compound, [Co(C(14)H(10)Br(2)NO)(2)], the Co(II) ion is coordinated by an O and an N atom from two equivalent 2-[(E)-benzyl-imino-meth-yl]-4,6-dibromo-phenolate ligands, displaying a distorted tetra-hedral geometry. The Co(II) ion occupies a special position on a twofold rotation axis and thus the mol-ecular symmetry of the complex is C(2). The two phenolate rings are perpendicular [89.8?(3)°].

| S-EPMC2959770 | biostudies-literature

2-{[(2-Hy-droxy-3,5-dimethyl-benz-yl)(meth-yl)amino]-meth-yl}-4,6-dimethyl-phenol.

Project description:In the title compound, C(19)H(25)NO(2), the dihedral angle between the benzene rings is 53.15?(8)°. One of the -OH groups forms an intra-molecular O-H?N link, generating an S(6) ring. The other -OH group forms an inter-molecular O-H?N hydrogen bond in the crystal, generating centrosymmetric R(2) (2)(20) loops.

| S-EPMC3379400 | biostudies-literature

Bis(?-2-{1-[2-(dimethyl-amino)-ethyl-imino]-eth-yl}phenolato)bis-[bromido-copper(II)] monohydrate.

Project description:In the centrosymmetric dinuclear copper(II) title complex, [Cu(2)Br(2)(C(12)H(17)N(2)O)(2)]·H(2)O, each Cu(II) ion is five coordinated in a square-pyramidal geometry by the N,N',O-tridentate Schiff base, one Br atom and the bridging O atom of the centrosymmetrically related Schiff base. In the crystal, the water mol-ecules link the complex mol-ecules into infinite chains along the b axis via O-H?Br and C-H?O hydrogen bonds.

| S-EPMC3151890 | biostudies-other

(?-4-Bromo-2-{1-[2-(dimethyl-amino)ethyl-imino]eth-yl}phenolato)bis-[ethyl-zinc(II)].

Project description:The title complex, [Zn(2)(C(2)H(5))(2)(C(12)H(16)BrN(2)O)(2)], is dimeric, bridged through the O atoms of the phenolate anions. The molecule lies on a crystallographic twofold rotation axis. Each Zn atom is penta-coordinated by two N atoms and two bridging O atoms of the tridentate salicylideneiminate ligands and one C atom from an ethyl group, forming a distorted square-pyramidal environment.

| S-EPMC2915078 | biostudies-literature

Bis{2,4-dichloro-6-[3-(dimethyl-amino)propyl-imino-meth-yl]phenolato}copper(II).

Project description:In the title complex, [Cu(C(12)H(15)Cl(2)N(2)O)(2)], the Cu(II) ion is coordinated by one N,O-bidentate and one N,N',O-tridentate Schiff base ligand, resulting in a distorted CuN(3)O(2) square-based pyramidal coordination for the metal ion, with the O atoms lying trans to each other in the basal plane.

| S-EPMC2970479 | biostudies-literature

Diazido-bis{2-[3-(dimethyl-amino)propyl-imino-meth-yl]phenol}manganese(III) perchlorate.

Project description:The title compound, [Mn(N(3))(2)(C(12)H(18)N(2)O)(2)]ClO(4), was synthesized from manganese(III) acetate, sodium azide and 2-[3-(dimethyl-amino)propyl-imino-meth-yl]phenol by a hydro-thermal reaction. The Mn(III) ion is hexa-coordinated by two N and two O atoms from two phenolate ligands and two N atoms from two azide ligands. The Mn(III) cation lies on an inversion centre and, as a result, the asymmetric unit comprises one half-mol-ecule.

| S-EPMC2961989 | biostudies-literature

Crystal structure of di-chlorido-bis-{μ-2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}{2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}cadmium(II)cobalt(III) monohydrate.

Project description:The title compound, [CoCd(C9H10NO2)3Cl2]·H2O, is a solvatomorph of the corresponding hemihydrate recently published by us [Nesterova et al. (2018 ▸). Appl. Cat. A, 560, 171-184]. The current structure reveals different cell parameters and space group compared with the published one while both are monoclinic with almost the same cell volume. The title compound is formed of discrete neutral dinuclear mol-ecules with no crystallographically imposed symmetry and water mol-ecules of crystallization. The overall geometry about the cobalt(III) ion is octa-hedral with an N3O3 environment; each ligand acts as a meridional ONO donor. The CdII coordination sphere approximates an irregular square pyramid with a chlorine atom at the apex. There is significant shortening of a Cd-O bond length to the oxygen atom of the methoxo group on one of the ligands [2.459 (3) Å] compared to the corresponding distance in the published structure [2.724 (7) Å], while other Cd-Cl/N/O bonds remain roughly the same. In the crystal lattice, the heterometallic mol-ecules, which are related by the crystallographic n-glide plane and inter-linked by weak hydrogen bonds to solvent water mol-ecules, form columns along [101]. Adjacent columns lie anti-parallel to each other.

| S-EPMC6218914 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data