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Bis{2-[2-(dimethyl-amino)ethyl-imino-meth-yl]-4,6-disulfanylphenolato}cobalt(II) monohydrate.


ABSTRACT: In the title hydrated complex, [Co(C(11)H(15)N(2)OS(2))(2)]·H(2)O, the Co(II) atom (site symmetry 2) is coordinated by two O,N,N'-tridentate Schiff base ligands, resulting in a very distorted cis-CoO(2)N(4) octa-hedral geometry for the metal ion. In the crystal, the water mol-ecule (O-atom site symmetry 2) inter-acts with nearby complex mol-ecules by way of bifurcated O-H?(O,S) hydrogen bonds.

SUBMITTER: Cai YJ 

PROVIDER: S-EPMC2970116 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

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Bis{2-[2-(dimethyl-amino)ethyl-imino-meth-yl]-4,6-disulfanylphenolato}cobalt(II) monohydrate.

Cai Ying-Jie YJ   Li Jin J   Huang Peng P   Zeng Qing-Fu QF  

Acta crystallographica. Section E, Structure reports online 20090829 Pt 9


In the title hydrated complex, [Co(C(11)H(15)N(2)OS(2))(2)]·H(2)O, the Co(II) atom (site symmetry 2) is coordinated by two O,N,N'-tridentate Schiff base ligands, resulting in a very distorted cis-CoO(2)N(4) octa-hedral geometry for the metal ion. In the crystal, the water mol-ecule (O-atom site symmetry 2) inter-acts with nearby complex mol-ecules by way of bifurcated O-H⋯(O,S) hydrogen bonds. ...[more]

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