Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis{2-[3-(dimethyl-amino)propyl-imino-meth-yl]-4,6-disulfanylphenolato}cobalt(II).

ABSTRACT: In the title mononuclear complex, [Co(C(12)H(17)N(2)OS(2))(2)], the Co(II) atom is four-coordinated by two N,O-bidentate Schiff base ligands, resulting in a slightly distorted trans-CoN(2)O(2) square-planar coordination.

SUBMITTER: Li HY

PROVIDER: S-EPMC2970151 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis{2-[3-(dimethyl-amino)propyl-imino-meth-yl]-4,6-disulfanylphenolato}cobalt(II).

Li Hai-Yan HY Wang Li-Jun LJ Wang Qiang Q Zeng Qing-Fu QF

Acta crystallographica. Section E, Structure reports online 20090815 Pt 9

In the title mononuclear complex, [Co(C(12)H(17)N(2)OS(2))(2)], the Co(II) atom is four-coordinated by two N,O-bidentate Schiff base ligands, resulting in a slightly distorted trans-CoN(2)O(2) square-planar coordination. ...[more]

PMID: 21577427

Similar Datasets

Bis{2-[2-(dimethyl-amino)ethyl-imino-meth-yl]-4,6-disulfanylphenolato}cobalt(II) monohydrate.

Project description:In the title hydrated complex, [Co(C(11)H(15)N(2)OS(2))(2)]·H(2)O, the Co(II) atom (site symmetry 2) is coordinated by two O,N,N'-tridentate Schiff base ligands, resulting in a very distorted cis-CoO(2)N(4) octa-hedral geometry for the metal ion. In the crystal, the water mol-ecule (O-atom site symmetry 2) inter-acts with nearby complex mol-ecules by way of bifurcated O-H?(O,S) hydrogen bonds.

| S-EPMC2970116 | biostudies-literature

Bis{2-[3-(dimethyl-amino)propyl-imino-meth-yl]-4,6-dihydro-seleno-phenolato}zinc(II).

Project description:In the title complex, [Zn(C(12)H(17)N(2)OSe(2))(2)], the Zn(II) ion is six-coordinated by two N,N',O-tridentate Schiff base ligands, resulting in a slightly distorted trans-ZnO(2)N(4) octa-hedral coordination for the metal ion.

| S-EPMC2969977 | biostudies-literature

Bis{2,4-dichloro-6-[3-(dimethyl-amino)propyl-imino-meth-yl]phenolato}copper(II).

Project description:In the title complex, [Cu(C(12)H(15)Cl(2)N(2)O)(2)], the Cu(II) ion is coordinated by one N,O-bidentate and one N,N',O-tridentate Schiff base ligand, resulting in a distorted CuN(3)O(2) square-based pyramidal coordination for the metal ion, with the O atoms lying trans to each other in the basal plane.

| S-EPMC2970479 | biostudies-literature

Bis{2-[3-(dimethyl-amino)propyl-imino-meth-yl]-6-methoxy-phenolato-κN,N',O}nickel(II).

Project description:The centrosymmetric title complex, [Ni(C(13)H(19)N(2)O(2))(2)], is a mononuclear nickel(II) complex. The Ni(II) atom is coordinated by four N atoms and two O atoms of two deprotonated Schiff base ligands, forming a slightly distorted octa-hedral coordination configuration, in which the tertiary N atoms occupy the axial positions.

| S-EPMC2961932 | biostudies-literature

Diazido-bis{2-[3-(dimethyl-amino)propyl-imino-meth-yl]phenol}manganese(III) perchlorate.

Project description:The title compound, [Mn(N(3))(2)(C(12)H(18)N(2)O)(2)]ClO(4), was synthesized from manganese(III) acetate, sodium azide and 2-[3-(dimethyl-amino)propyl-imino-meth-yl]phenol by a hydro-thermal reaction. The Mn(III) ion is hexa-coordinated by two N and two O atoms from two phenolate ligands and two N atoms from two azide ligands. The Mn(III) cation lies on an inversion centre and, as a result, the asymmetric unit comprises one half-mol-ecule.

| S-EPMC2961989 | biostudies-literature

Bis{2-[(E)-benzyl-imino-meth-yl]-4,6-dibromo-phenolato-κN,O}cobalt(II).

Project description:In the title compound, [Co(C(14)H(10)Br(2)NO)(2)], the Co(II) ion is coordinated by an O and an N atom from two equivalent 2-[(E)-benzyl-imino-meth-yl]-4,6-dibromo-phenolate ligands, displaying a distorted tetra-hedral geometry. The Co(II) ion occupies a special position on a twofold rotation axis and thus the mol-ecular symmetry of the complex is C(2). The two phenolate rings are perpendicular [89.8 (3)°].

| S-EPMC2959770 | biostudies-literature

cis-Bis[2-(cyclo-propyl-imino-meth-yl)-6-methoxy-phenolato]bis-(thio-cyanato)cobalt(II).

Project description:In the title compound, [Co(NCS)(2)(C(11)H(13)NO(2))(2)], a mononuclear Schiff base cobalt(II) complex, the Co atom is six-coordinated by four O atoms from two Schiff base ligands, and by two N atoms from two thio-cyanate ligands, forming a distorted octa-hedral geometry. The central Co atom lies on a twofold rotation axis. An intramolecular N-H⋯O hydrogen bond is present.

| S-EPMC2914956 | biostudies-literature

Bis{2-meth-oxy-6-[3-(methyl-amino)propyl-imino-meth-yl]phenolato}nickel(II) bis-(perchlorate).

Project description:The asymmetric unit of the title compound, [Ni(C(12)H(18)N(2)O(2))(2)](ClO(4))(2), consists of one-half of a centrosymmetric mononuclear Schiff base nickel(II) complex cation and one perchlorate anion. The Ni(II) ion, lying on the inversion center, is coordinated by two N atoms and two O atoms from two Schiff base ligands, forming a square-planar geometry. The crystal packing is stabilized by N-H⋯O hydrogen bonds.

| S-EPMC2961174 | biostudies-literature

Bis{2-[3-(dimethyl-amino)-propyl-imino-meth-yl]-6-meth-oxy-phenolato}-?N,N',O;?N,O-zinc(II) dihydrate.

Project description:In the title mononuclear Zn(II) complex, [Zn(C(13)H(19)N(2)O(2))(2)]·2H(2)O, the Zn(II) atom is coordinated by two O atoms and three N atoms from two crystallographically different Schiff base ligands in a distorted trigonal-bipyramidal environment. One O and two N atoms constitute the base of the pyramid, and one O and one N atoms occupy the apical positions. Inter-molecular O-H?O and O-H?N hydrogen bonds between the lattice water mol-ecules and N/O atoms of the Schiff base ligands stabilize the conformation, whereas inter-molecular O-H?O hydrogen bonds between the two lattice water mol-ecules lead to a chain structure in [001].

| S-EPMC3050366 | biostudies-literature

Bis[2-(cyclo-propyl-imino-meth-yl)-5-methoxy-phenolato]zinc(II).

Project description:In the title complex, [Zn(C(11)H(12)NO(2))(2)], the Zn(2+) ion (site symmetry 2) is coordinated by two N,O-bidentate Schiff base ligands, generating a tetra-hedral ZnO(2)N(2) geometry for the metal ion.

| S-EPMC2979218 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data