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Poly[diaqua-?(2)-oxalato-di-?(4)-terephthalato-dilutetium(III)].

ABSTRACT: In the title compound, [Lu(2)(C(8)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), the Lu(3+) cations are each coordinated by eight O atoms of four terephthalate anions, one oxalate anion and one aqua ligand to complete a distorted square-anti-prismatic geometry. They are bridged by the terephthalate ligands, generating a three-dimensional framework, which is further stabilized by the oxalate ligands. The terephthalate ions and oxalate ions are all located on centers of inversion.

SUBMITTER: Li ZF

PROVIDER: S-EPMC2970178 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-dilutetium(III)].

Li Zhi-Feng ZF Wang Chun-Xiang CX

Acta crystallographica. Section E, Structure reports online 20090905 Pt 10

In the title compound, [Lu(2)(C(8)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), the Lu(3+) cations are each coordinated by eight O atoms of four terephthalate anions, one oxalate anion and one aqua ligand to complete a distorted square-anti-prismatic geometry. They are bridged by the terephthalate ligands, generating a three-dimensional framework, which is further stabilized by the oxalate ligands. The terephthalate ions and oxalate ions are all located on centers of inversion. ...[more]

PMID: 21577697

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