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Methyl (S(p))-2-(diphenyl-phosphino)ferrocene-1-carboxyl-ate.

ABSTRACT: The title compound, [Fe(C(5)H(5))(C(19)H(16)O(2)P)], obtained serendipitously during recrystallization of 1-hydroxy-benzotriazolyl (S(p))-2-(diphenyl-phosphino)ferrocene-1-carboxyl-ate from meth-anol, crystallizes in the chiral space group P2(1)2(1)2(1). Its crystal structure not only confirms the anti-cipated absolute configuration but also establishes a rather regular geometry for the ferrocene unit, devoid of any significant deformation due to the attached substituents. In the crystal, symmetry-related mol-ecules are linked via weak C-H?O inter-actions.

SUBMITTER: Stepnicka P

PROVIDER: S-EPMC2970334 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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Methyl (S(p))-2-(diphenyl-phosphino)ferrocene-1-carboxyl-ate.

Stěpnička Petr P Tauchman Jiří J Císařová Ivana I

Acta crystallographica. Section E, Structure reports online 20090916 Pt 10

The title compound, [Fe(C(5)H(5))(C(19)H(16)O(2)P)], obtained serendipitously during recrystallization of 1-hydroxy-benzotriazolyl (S(p))-2-(diphenyl-phosphino)ferrocene-1-carboxyl-ate from meth-anol, crystallizes in the chiral space group P2(1)2(1)2(1). Its crystal structure not only confirms the anti-cipated absolute configuration but also establishes a rather regular geometry for the ferrocene unit, devoid of any significant deformation due to the attached substituents. In the crystal, symmet ...[more]

PMID: 21577740

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