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[?-1,1'-Bis(diphenyl-phosphino)ferrocene-?P:P']bis-{[(Z)-O-isopropyl-N-(4-methyl-phen-yl)thio-carbamato-?S]gold(I)}.

ABSTRACT: In the title compound, [Au(2)Fe(C(11)H(14)NOS)(2)(C(17)H(14)P)(2)], the Fe(II) atom is located on a crystallographic centre of inversion. For the Au(I) atom, the deviation from linearity defined by its S,P-donor set [S-Au-P = 178.17?(8)?Å] is due to an intra-molecular Au?O contact [3.079?(4)?Å]. In the crystal, supra-molecular chains mediated by C-H?N inter-actions are formed, which run parallel to [001].

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2971759 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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[μ-1,1'-Bis(diphenyl-phosphino)ferrocene-κP:P']bis-{[(Z)-O-isopropyl-N-(4-methyl-phen-yl)thio-carbamato-κS]gold(I)}.

Tadbuppa Primjira P PP Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091118 Pt 12

In the title compound, [Au(2)Fe(C(11)H(14)NOS)(2)(C(17)H(14)P)(2)], the Fe(II) atom is located on a crystallographic centre of inversion. For the Au(I) atom, the deviation from linearity defined by its S,P-donor set [S-Au-P = 178.17 (8) Å] is due to an intra-molecular Au⋯O contact [3.079 (4) Å]. In the crystal, supra-molecular chains mediated by C-H⋯N inter-actions are formed, which run parallel to [001]. ...[more]

PMID: 21578625

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