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Bis(1,3-dibutylthiourea)dicyanido-mercury(II).

ABSTRACT: In the title compound, [Hg(CN)(2)(C(9)H(20)N(2)S)(2)], the Hg atom lies on a twofold rotation axis. There is only half a mol-ecule in the asymmetric unit. The Hg atom has a distorted tetra-hedral coordination involving the S atoms of two 1-butyl-3-propyl-thio-urea groups and the C atoms of the two CN(-) anions. In the crystal packing, adjacent mol-ecules are connected by inter-molecular N-H?N and N-H?S hydrogen bonds, forming infinite chains in three dimensions.

SUBMITTER: Ahmad S

PROVIDER: S-EPMC2970451 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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Bis(1,3-dibutylthiourea)dicyanido-mercury(II).

Ahmad Saeed S Sadaf Haseeba H Akkurt Mehmet M Sharif Shahzad S Khan Islam Ullah IU

Acta crystallographica. Section E, Structure reports online 20090909 Pt 10

In the title compound, [Hg(CN)(2)(C(9)H(20)N(2)S)(2)], the Hg atom lies on a twofold rotation axis. There is only half a mol-ecule in the asymmetric unit. The Hg atom has a distorted tetra-hedral coordination involving the S atoms of two 1-butyl-3-propyl-thio-urea groups and the C atoms of the two CN(-) anions. In the crystal packing, adjacent mol-ecules are connected by inter-molecular N-H⋯N and N-H⋯S hydrogen bonds, forming infinite chains in three dimensions. ...[more]

PMID: 21577723

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