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{2-Hydr-oxy-N'-[1-(2-oxidophenyl)ethyl-idene]benzohydrazidato}morpholinecopper(II).

ABSTRACT: The Cu(II) ion in the title complex, [Cu(C(15)H(12)N(2)O(3))(C(4)H(9)NO)], is coordinated by one carbonyl O atom, one hydrazine N atom and one phenolate O atom from the doubly deprotonated tridentate ligand and one N atom from a morpholine mol-ecule, forming a distorted trans-CuN(2)O(2) square-planar coordination geometry. An intra-molecular O-H⋯N hydrogen bond occurs within the ligand, generating an S(6) ring.

SUBMITTER: Lin SZ

PROVIDER: S-EPMC2970954 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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{2-Hydr-oxy-N'-[1-(2-oxidophenyl)ethyl-idene]benzohydrazidato}morpholinecopper(II).

Lin Song-Zhu SZ Jia Ruo-Kun RK Yuan Yan-Lin YL Zhan Peng P

Acta crystallographica. Section E, Structure reports online 20091023 Pt 11

The Cu(II) ion in the title complex, [Cu(C(15)H(12)N(2)O(3))(C(4)H(9)NO)], is coordinated by one carbonyl O atom, one hydrazine N atom and one phenolate O atom from the doubly deprotonated tridentate ligand and one N atom from a morpholine mol-ecule, forming a distorted trans-CuN(2)O(2) square-planar coordination geometry. An intra-molecular O-H⋯N hydrogen bond occurs within the ligand, generating an S(6) ring. ...[more]

PMID: 21578158

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