Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(1H-Imidazole-?N) {N-[1-(2-oxidophenyl-?O)ethyl-idene]-l-phenyl-alaninato-?N,O}copper(II).

ABSTRACT: In the title compound, [Cu(C(17)H(15)NO(3))(C(3)H(4)N(2))], the Cu(II) atom is four-coordinated by two O atoms and the N atom of the tridentate Schiff base ligand, and one N atom from the imidazole ligand in a distorted square-planar geometry. In the crystal structure, mol-ecules are linked into dimers by inter-molecular N-H?O hydrogen bonds.

SUBMITTER: Han YJ

PROVIDER: S-EPMC2959325 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(1H-Imidazole-κN) {N-[1-(2-oxidophenyl-κO)ethyl-idene]-l-phenyl-alaninato-κN,O}copper(II).

Han Yong-Jun YJ Zhao Gan-Qing GQ Zhao Xiao-Jun XJ Song Wen-Li WL Shi Jie-Li JL

Acta crystallographica. Section E, Structure reports online 20080906 Pt 10

In the title compound, [Cu(C(17)H(15)NO(3))(C(3)H(4)N(2))], the Cu(II) atom is four-coordinated by two O atoms and the N atom of the tridentate Schiff base ligand, and one N atom from the imidazole ligand in a distorted square-planar geometry. In the crystal structure, mol-ecules are linked into dimers by inter-molecular N-H⋯O hydrogen bonds. ...[more]

PMID: 21200988

Similar Datasets

Bromidotetra-kis-(2-ethyl-1H-imidazole-?N (3))copper(II) bromide.

Project description:The Cu(II) ion in the title mol-ecular salt, [CuBr(C5H8N2)4]Br, is coordinated in a square-pyramidal geometry by four N atoms of imidazole ligands and one bromide anion in the apical position. In the crystal, the ions are linked by N-H?Br hydrogen bonds involving both the coordinating and the free bromide species as acceptors. A C-H?Br inter-action is also observed. Overall, a three-dimensional network results.

| S-EPMC3588773 | biostudies-literature

Bromidotetra-kis-(1H-2-ethyl-5-methyl-imidazole-?N)copper(II) bromide.

Project description:The Cu(II) ion in the title compound, [CuBr(C(6)H(10)N(2))(4)]Br, is coordinated in a square-based-pyramidal geometry by the N atoms of four imidazole ligands and a bromide anion in the apical site. Both the Cu(II) and Br(-) atoms lie on a crystallographic fourfold axis. In the crystal, the [CuBr(C(6)H(10)N(2))(4)](+) complex cations are linked to the uncoordinated Br(-) anions (site symmetry [Formula: see text]) by N-H?Br hydrogen bonds, generating a three-dimensional network. The ethyl group of the imidazole ligand was modelled as disordered over two orientations with occupancies of 0.620?(8) and 0.380?(8).

| S-EPMC3238785 | biostudies-literature

[Bis(3,5-dimethyl-pyrazol-1-yl)methane]{N-[1-(2-oxidophen-yl)ethyl-idene]-dl-alaninato}copper(II) monohydrate.

Project description:In the title compound, [Cu(C(11)H(11)NO(3))(C(11)H(16)N(4))]·H(2)O, the Cu(II) atom is five-coordinate in a distorted square-pyramidal geometry. The basal positions are occupied by three donor atoms from the tridentate Schiff base ligand and by one N atom from a bis-(3,5-dimethyl-prazol-l-yl)methane ligand. The apical position is occupied by the N atom of the other ligand of this type. There are only van der Waals contacts in the crystal structure.

| S-EPMC2960032 | biostudies-literature

{2-Hydr-oxy-N'-[1-(2-oxidophenyl)ethyl-idene]benzohydrazidato}morpholinecopper(II).

Project description:The Cu(II) ion in the title complex, [Cu(C(15)H(12)N(2)O(3))(C(4)H(9)NO)], is coordinated by one carbonyl O atom, one hydrazine N atom and one phenolate O atom from the doubly deprotonated tridentate ligand and one N atom from a morpholine mol-ecule, forming a distorted trans-CuN(2)O(2) square-planar coordination geometry. An intra-molecular O-H⋯N hydrogen bond occurs within the ligand, generating an S(6) ring.

| S-EPMC2970954 | biostudies-literature

Bis(3,5-dimethyl-pyrazole)[N-salicyl-idene-?-alaninato(2-)]copper(II) dihydrate.

Project description:In the title compound, [Cu(C(10)H(10)NO(3))(C(5)H(8)N(2))(2)]·2H(2)O, the Cu(II) atom is coordinated by three N atoms and two O atoms in a distorted square-pyramidal geometry. The crystal packing is stabilized by inter-molecular O-H?O and N-H?O hydrogen bonds.

| S-EPMC2915162 | biostudies-literature

(Imidazole-?N){N-[1-(2-oxidophenyl)ethylidene]-l-valinato-?O,N,O'}copper(II).

Project description:In each of the two independent mol-ecules in the asymmetric unit of the title compound, [Cu(C(13)H(15)NO(3))(C(3)H(4)N(2))], the Cu(II) atom is four-coordinated by two O atoms and the N atom of the tridentate Schiff base ligand and one N atom from the imidazole ligand in a distorted square-planar geometry. In the crystal structure, mol-ecules are linked by inter-molecular N-H?O hydrogen bonds.

| S-EPMC2959304 | biostudies-literature

Di-μ-nitrito-κO:O-bis-[bis-(1-ethyl-1H-imidazole-κN)(nitrito-κO)copper(II)].

Project description:In the structure of the title compound, [Cu(2)(NO(2))(4)(C(5)H(8)N(2))(4)], the asymmetric unit consists of two moieties containing one Cu ion, two nitrite ions and two 1-ethyl-1H-imidazole mol-ecules associated via weak Cu-O inter-actions. Each Cu(II) atom displays an elongted square-pyramidal CuN(2)O(3) coordination geometry with a slight tetra-hedral distortion in the basal plane. The dimeric units are linked into a three-dimensional network by C-H⋯O hydrogen bonds.

| S-EPMC3151931 | biostudies-literature

catena-Poly[[bis-(1-ethyl-1H-imidazole-κN)copper(II)]-μ-oxalato-κO,O:O,O].

Project description:The title compound, [Cu(C(2)O(4))(C(5)H(8)N(2))(2)](n), is composed of one-dimensional linear chains running parallel to the a axis. In the chain, trans-[Cu(imidazole)(2)](2+) units are sequentially bridged by bis-bidentate oxalate ligands, resulting in an octa-hedral CuO(4)N(2) donor set. The Cu⋯Cu separation through the oxalate bridge is 5.620 (5) Å. Both the Cu atoms and the C-C bond of the oxalate bridge are bis-ected by inversion centres.

| S-EPMC3246998 | biostudies-literature

Bis(2-ethyl-1H-imidazole-?N)bis-(nitrito-?O,O')copper(II) dihydrate.

Project description:In the title compound, [Cu(NO(2))(2)(C(5)H(8)N(2))]·2H(2)O, the Cu(2+) ion exhibits site symmetry 2 and is hexacoordinated by four O atoms from two nitrite ions and two N atoms from two 2-ethyl-1H-imidazole mol-ecules. A free water mol-ecule assists in forming a three-dimensional network holding together the complexes via O-H?N, O-H?O and N-H?O hydrogen bonds.

| S-EPMC3151815 | biostudies-other

Tris(2-ethyl-1H-imidazole-?N)(terephthalato-?O)zinc(II).

Project description:The title compound, [Zn(C(8)H(4)O(4))(C(5)H(8)N(2))(3)], has a neutral monomeric structure in which one terephthalate dianion and three 2-ethyl-1H-imidazole ligands coordinate to the Zn(II) ion in a distorted tetra-hedral geometry. The methyl group of one of the ethyl groups is disordered over two positions with occupancies of 0.66?(2) and 0.34?(2). In the crystal structure, mol-ecules are linked into a three-dimensional hydrogen-bonded network by inter-molecular N-H?O interactions involving the uncoordinated carboxyl-ate O atoms.

| S-EPMC2977618 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data