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Bis(2-hydroxy-benzaldehyde oximato-?O)triphenyl-anti-mony(V).

ABSTRACT: The mol-ecule of the title compound, [Sb(C(6)H(5))(3)(C(7)H(6)NO(2))(2)], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The Sb center has a slightly distorted trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of symmetry-related 2-hydroxy-benzaldehyde oximate ligands. An intra-molecular O-H?N inter-action is present. The crystal structure is stabilized by C-H?O inter-actions.

SUBMITTER: Dong L

PROVIDER: S-EPMC2971330 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Bis(2-hydroxy-benzaldehyde oximato-κO)triphenyl-anti-mony(V).

Dong Lei L Yin Handong H Wen Liyuan L Wang Daqi D

Acta crystallographica. Section E, Structure reports online 20091028 Pt 11

The mol-ecule of the title compound, [Sb(C(6)H(5))(3)(C(7)H(6)NO(2))(2)], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The Sb center has a slightly distorted trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of symmetry-related 2-hydroxy-benzaldehyde oximate ligands. An intra-molecular O-H⋯N inter-action is present. The crystal structure is stabilized by C-H⋯O inter-actions. ...[more]

PMID: 21578170

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