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Catena-Poly[[[acetonitrile-copper(I)]-bis-[?-bis-(diphenyl-phosphino)methane-?P:P']-copper(I)-?-1,2-di-4-pyridy-l-ethene] bis-(tetra-fluoridoborate)].

ABSTRACT: The title dinuclear copper(I) complex, {[Cu(2)(C(2)H(3)N)(C(12)H(10)N(2))(C(25)H(22)P(2))(2)](BF(4))(2)}(n), contains 1,2-di-4-pyridyl-ethene, bis-(diphenyl-phosphino)methane and acetonitrile ligands. The two Cu atoms, one with an N(2)P(2) ligand set and the other with an NP(2) ligand set, are bridged by two bis-(diphenyl-phosphino)methane ligands, forming an eight-membered ring.

SUBMITTER: Wang Y

PROVIDER: S-EPMC2971055 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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catena-Poly[[[acetonitrile-copper(I)]-bis-[μ-bis-(diphenyl-phosphino)methane-κP:P']-copper(I)-μ-1,2-di-4-pyridy-l-ethene] bis-(tetra-fluoridoborate)].

Wang Yufei Y Gan Xin X Jishu Chen C

Acta crystallographica. Section E, Structure reports online 20091013 Pt 11

The title dinuclear copper(I) complex, {[Cu(2)(C(2)H(3)N)(C(12)H(10)N(2))(C(25)H(22)P(2))(2)](BF(4))(2)}(n), contains 1,2-di-4-pyridyl-ethene, bis-(diphenyl-phosphino)methane and acetonitrile ligands. The two Cu atoms, one with an N(2)P(2) ligand set and the other with an NP(2) ligand set, are bridged by two bis-(diphenyl-phosphino)methane ligands, forming an eight-membered ring. ...[more]

PMID: 21578112

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