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Bis[cis-bis-(diphenyl-phosphino)ethene-?P,P']copper(I) tetra-fluoridoborate ethanol solvate.

ABSTRACT: In the title compound [Cu(C(26)H(22)P(2))(2)]BF(4)·C(2)H(5)OH, a disordered ethanol solvate molecule and the anions are located in well defined channels along the c axis. The four-coordinate Cu(P-P)(2) core of the cation adopts approximately D(2) point group symmetry with the Cu-P bond lengths spanning a narrow range from 2.272?(1) to 2.285?(1)?Å.

SUBMITTER: Healy PC

PROVIDER: S-EPMC2977563 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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Bis[cis-bis-(diphenyl-phosphino)ethene-κP,P']copper(I) tetra-fluoridoborate ethanol solvate.

Healy Peter C PC Loughrey Bradley T BT Williams Michael L ML

Acta crystallographica. Section E, Structure reports online 20090408 Pt 5

In the title compound [Cu(C(26)H(22)P(2))(2)]BF(4)·C(2)H(5)OH, a disordered ethanol solvate molecule and the anions are located in well defined channels along the c axis. The four-coordinate Cu(P-P)(2) core of the cation adopts approximately D(2) point group symmetry with the Cu-P bond lengths spanning a narrow range from 2.272 (1) to 2.285 (1) Å. ...[more]

PMID: 21583749

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