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Catena-Poly[[sodium-di-?-?-d-glucose] chloride].

ABSTRACT: The asymmetric unit of the title compound, {[Na(C(6)H(12)O(6))(2)]Cl}(n), contains six glucose mol-ecules, three Na(+) ions and three Cl(-) ions, i.e. three independent {[Na(C(6)H(12)O(6))(2)]Cl} units. Each of these units forms polymeric chains along the c axis. Each Na(+) ion is surrounded by six O atoms from four glucose mol-ecules, forming a distorted octa-hedral geometry. All glucose mol-ecules adopt chair conformations. The constituent units are linked into a three-dimensional framework by O-H?Cl and O-H?O hydrogen bonds, utilizing all the O-H groups.

SUBMITTER: Wong KC

PROVIDER: S-EPMC2971272 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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catena-Poly[[sodium-di-μ-β-d-glucose] chloride].

Wong K C KC Hamid Abdul A Baharuddin S S Quah Ching Kheng CK Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20091007 Pt 11

The asymmetric unit of the title compound, {[Na(C(6)H(12)O(6))(2)]Cl}(n), contains six glucose mol-ecules, three Na(+) ions and three Cl(-) ions, i.e. three independent {[Na(C(6)H(12)O(6))(2)]Cl} units. Each of these units forms polymeric chains along the c axis. Each Na(+) ion is surrounded by six O atoms from four glucose mol-ecules, forming a distorted octa-hedral geometry. All glucose mol-ecules adopt chair conformations. The constituent units are linked into a three-dimensional framework by ...[more]

PMID: 21578072

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