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Catena-Poly[sodium(I)-?-tetra-butoxy-borato].

ABSTRACT: The title compound, [Na(C(16)H(36)BO(4))](n), has a fourfold axis passing through the Na and B atoms which both are bound by four O atoms. The tetra-butoxy-borate anion provides the bridging to form one-dimensional polymers running along [001], just like those found for the tetra-ethoxy-borate structure. The two but-oxy 'tail' atoms are disordered over two conformations in a 0.887?(9):0.113?(9) ratio.

SUBMITTER: Gainsford GJ

PROVIDER: S-EPMC2977560 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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catena-Poly[sodium(I)-μ-tetra-butoxy-borato].

Gainsford Graeme J GJ Kemmitt Tim T

Acta crystallographica. Section E, Structure reports online 20090408 Pt 5

The title compound, [Na(C(16)H(36)BO(4))](n), has a fourfold axis passing through the Na and B atoms which both are bound by four O atoms. The tetra-butoxy-borate anion provides the bridging to form one-dimensional polymers running along [001], just like those found for the tetra-ethoxy-borate structure. The two but-oxy 'tail' atoms are disordered over two conformations in a 0.887 (9):0.113 (9) ratio. ...[more]

PMID: 21583746

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