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Bis(2-imino-methyl-5-methoxy-phenolato)nickel(II).

ABSTRACT: The title compound, [Ni(C(8)H(8)NO(2))(2)], is a centrosymmetric mononuclear nickel(II) complex. The Ni(II) ion, lying on an inversion centre, is four-coordinated in a square-planar geometry by two phenolate O and two imine N atoms from two symmetry-related 2-imino-methyl-5-methoxy-phenolate ligands. In the crystal, mol-ecules are linked into corrugated layers parallel to (100) by N-H?O hydrogen bonds.

SUBMITTER: Tang C

PROVIDER: S-EPMC2971283 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Bis(2-imino-methyl-5-methoxy-phenolato)nickel(II).

Tang Chunbao C

Acta crystallographica. Section E, Structure reports online 20091003 Pt 11

The title compound, [Ni(C(8)H(8)NO(2))(2)], is a centrosymmetric mononuclear nickel(II) complex. The Ni(II) ion, lying on an inversion centre, is four-coordinated in a square-planar geometry by two phenolate O and two imine N atoms from two symmetry-related 2-imino-methyl-5-methoxy-phenolate ligands. In the crystal, mol-ecules are linked into corrugated layers parallel to (100) by N-H⋯O hydrogen bonds. ...[more]

PMID: 21578047

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