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Bis(2-hydroxy-imino-methyl-6-methoxy-phenolato-?O,N)nickel(II).

ABSTRACT: The Ni atom in the title compound, [Ni(C(8)H(8)NO(3))(2)], lies on a center of inversion in a square-planar coordination enviroment. The hydroxyl group of one anion forms a short hydrogen bond to the metal-coordinated O atom of the other anion.

SUBMITTER: Li BW

PROVIDER: S-EPMC2968630 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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Bis(2-hydroxy-imino-methyl-6-methoxy-phenolato-κO,N)nickel(II).

Li Bing-Wen BW Zeng Ming-Hua MH Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20090225 Pt 3

The Ni atom in the title compound, [Ni(C(8)H(8)NO(3))(2)], lies on a center of inversion in a square-planar coordination enviroment. The hydroxyl group of one anion forms a short hydrogen bond to the metal-coordinated O atom of the other anion. ...[more]

PMID: 21582092

Similar Datasets

Bis(2-imino-methyl-5-methoxy-phenolato)nickel(II).

Project description:The title compound, [Ni(C(8)H(8)NO(2))(2)], is a centrosymmetric mononuclear nickel(II) complex. The Ni(II) ion, lying on an inversion centre, is four-coordinated in a square-planar geometry by two phenolate O and two imine N atoms from two symmetry-related 2-imino-methyl-5-methoxy-phenolate ligands. In the crystal, mol-ecules are linked into corrugated layers parallel to (100) by N-H?O hydrogen bonds.

| S-EPMC2971283 | biostudies-literature

Bis(2-hydroxy-imino-methyl-6-methoxy-phenolato-κO,N)cobalt(II).

Project description:In the title compound, [Co(C(8)H(8)NO(3))(2)], the Co(II) atom lies on a centre of inversion and is coordinated in a slightly distorted square-planar geometry by two N and two O atoms from the 2-hydroxy-imino-methyl-6-methoxy-phenolate ligands. Intra-molecular O-H⋯O hydrogen bonds are formed and the complexes form stacks along the b axis, with an inter-planar separation of 3.332 (1) Å between complexes. Pairs of C-H⋯O contacts are formed between complexes in neighbouring stacks.

| S-EPMC2960033 | biostudies-literature

Bis(2-butyl-imino-methyl-5-methoxy-phenolato-κN,O)zinc(II).

Project description:In the centrosymmetric title compound, [Zn(C(12)H(16)NO(2))(2)], the Zn(II) centre is coordinated by two O,N-bidentate Schiff base ligands, resulting in a slightly distorted trans-ZnN(2)O(2) square-planar geometry for the metal ion. Two short intra-molecular C-H⋯O contacts occur in the mol-ecule.

| S-EPMC2970013 | biostudies-literature

Bis{2-[2-(isopropyl-ammonio)ethyl-imino-meth-yl]-6-methoxy-phenolato}nickel(II) dithio-cyanate.

Project description:The title complex, [Ni(C(13)H(20)N(2)O(2))(2)](NCS)(2), consists of a centrosymmetric mononuclear four-coordinate nickel(II) complex cation and two thio-cyanate anions. The Ni atom is located on an inversion center and is coordinated by two phenol O atoms and two imine N atoms from two equivalent Schiff base ligands, in a square-planar geometry. In the crystal structure, the amino H atoms are involved in N-H⋯O hydrogen bonds with the phenol and meth-oxy O atoms of the ligand, and in N-H⋯N hydrogen bonds with the N atoms of the thio-cyanate anions, which sit above and below the Ni atom.

| S-EPMC2960988 | biostudies-literature

Bis{2-[3-(dimethyl-amino)propyl-imino-meth-yl]-6-methoxy-phenolato-κN,N',O}nickel(II).

Project description:The centrosymmetric title complex, [Ni(C(13)H(19)N(2)O(2))(2)], is a mononuclear nickel(II) complex. The Ni(II) atom is coordinated by four N atoms and two O atoms of two deprotonated Schiff base ligands, forming a slightly distorted octa-hedral coordination configuration, in which the tertiary N atoms occupy the axial positions.

| S-EPMC2961932 | biostudies-literature

Bis{2-meth-oxy-6-[3-(methyl-amino)propyl-imino-meth-yl]phenolato}nickel(II) bis-(perchlorate).

Project description:The asymmetric unit of the title compound, [Ni(C(12)H(18)N(2)O(2))(2)](ClO(4))(2), consists of one-half of a centrosymmetric mononuclear Schiff base nickel(II) complex cation and one perchlorate anion. The Ni(II) ion, lying on the inversion center, is coordinated by two N atoms and two O atoms from two Schiff base ligands, forming a square-planar geometry. The crystal packing is stabilized by N-H⋯O hydrogen bonds.

| S-EPMC2961174 | biostudies-literature

Redetermination of bis-(2-formyl-phenolato-κO,O')nickel(II) as bis-[2-(imino-meth-yl)phenolato-κN,O']nickel(II).

Project description:The crystal structure of bis-(2-formyl-phenolato-κ(2)O,O')nickel(II), [Ni(C(7)H(5)O(2))(2)], a square-planar centrosymmetric complex, has been reported previously [Li & Chen (2006). Acta Cryst. E62, m1038-m1039]. However, a number of warning signs allows the assumption that the carbonyl group in the salicylaldehydate ligand of the claimed complex is incorrect. The crystal structure was therefore redetermined on basis of the originally deposited structure factors. After substituting the carbonyl O atom by an N atom, the model can be completed with an imine H atom, which was clearly discernible in a difference map. The resulting model, corresponding to bis-[2-(imino-meth-yl)phenolato-κ(2)N,O']nickel(II), [Ni(C(7)H(6)NO)(2)], converges well and none of the previous structural alerts remains. This reinter-pretation is also consistent with the published synthesis, which was carried out using salicylaldehyde in the presence of aqueous NH(3). The reinter-preted structure is virtually identical to earlier reports dealing with this bis-iminato Ni(II) complex.

| S-EPMC2979995 | biostudies-literature

Bis[2-(cyclo-hexyl-imino-meth-yl)-5-methoxy-phenolato]copper(II).

Project description:In the title centrosymmetric mononuclear complex, [Cu(C(14)H(18)NO(2))(2)], the Cu(II) ion, lying on an inversion centre, is four-coordinated by two imine N and two phenolate O atoms from two Schiff base ligands, forming a slightly distorted square-planar geometry.

| S-EPMC2980104 | biostudies-literature

Bis[2-(cyclo-propyl-imino-meth-yl)-5-methoxy-phenolato]zinc(II).

Project description:In the title complex, [Zn(C(11)H(12)NO(2))(2)], the Zn(2+) ion (site symmetry 2) is coordinated by two N,O-bidentate Schiff base ligands, generating a tetra-hedral ZnO(2)N(2) geometry for the metal ion.

| S-EPMC2979218 | biostudies-literature

trans-Bis(4-methoxy-thio-phenolato-κS)bis-(trimethyl-phosphine-κP)nickel(II).

Project description:The title compound, [Ni(C(7)H(7)OS)(2)(C(3)H(9)P)(2)], was obtained as a product of the reaction of [NiMe(2)(PMe(3))(3)] with two molar equivalents of 4-methoxy-thio-phenol in diethyl ether. The compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The Ni atom displays a square-planar coordination with two P-donor atoms lying in trans positions. The benzene rings of the thio-phenolate ligands are almost perpendicular to the square coordination plane, making dihedral angles of 80.43 (4) and 72.60 (4)°.

| S-EPMC2960343 | biostudies-literature

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