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(Disulfur dinitrido)triphenyl-anti-mony(V).

ABSTRACT: The title compound, [Sb(C(6)H(5))(3)(N(2)S(2))], contains a molecular entity that is very similar to that of the known polymorph of Sb(S(2)N(2))Ph(3) [Kunkel et al. (1997 ▶). Z. Naturforsch. Teil B, 52, 193-198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit is S-N=S=N, consisting of one long S-N bond, an inter-mediate length N=S bond and a short S=N bond.

SUBMITTER: Slawin AM

PROVIDER: S-EPMC2983911 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

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(Disulfur dinitrido)triphenyl-anti-mony(V).

Slawin Alexandra M Z AM Waddell Paul G PG Woollins J Derek JD

Acta crystallographica. Section E, Structure reports online 20100317 Pt 4

The title compound, [Sb(C(6)H(5))(3)(N(2)S(2))], contains a molecular entity that is very similar to that of the known polymorph of Sb(S(2)N(2))Ph(3) [Kunkel et al. (1997 ▶). Z. Naturforsch. Teil B, 52, 193-198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit is S-N=S=N, consisting of one long S-N bond, an inter-mediate length N=S bond and a short S=N bond. ...[more]

PMID: 21580516

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