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[(Z)-N-Isopropyl-O-methyl-thio-carbamato-?S](tri-p-tolyl-phosphine-?P)gold(I).

ABSTRACT: In the title compound, [Au(C(5)H(10)NOS)(C(21)H(21)P)], two independent mol-ecules comprise the asymmetric unit, and these are connected by an aurophilic inter-action [Au?Au = 3.1351?(3)?Å]. Each Au(I) atom is linearly coordinated within a S,P-donor set with the distortion from ideal linear geometry [S-Au-P = 175.31?(5) and 176.45?(5)°] ascribed to an intra-molecular Au?O contact in each case [2.974?(4) and 3.027?(4)?Å].

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2972070 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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[(Z)-N-Isopropyl-O-methyl-thio-carbamato-κS](tri-p-tolyl-phosphine-κP)gold(I).

Tadbuppa Primjira P PP Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091111 Pt 12

In the title compound, [Au(C(5)H(10)NOS)(C(21)H(21)P)], two independent mol-ecules comprise the asymmetric unit, and these are connected by an aurophilic inter-action [Au⋯Au = 3.1351 (3) Å]. Each Au(I) atom is linearly coordinated within a S,P-donor set with the distortion from ideal linear geometry [S-Au-P = 175.31 (5) and 176.45 (5)°] ascribed to an intra-molecular Au⋯O contact in each case [2.974 (4) and 3.027 (4) Å]. ...[more]

PMID: 21578594

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