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[(Z)-O-Isopropyl N-(m-tol-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

ABSTRACT: The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73?(3)°], with the distortion due in part to a close intra-molecular Au?O contact [3.060?(3)?Å]. In the crystal structure, mol-ecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H??.

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2983763 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

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[(Z)-O-Isopropyl N-(m-tol-yl)thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Tadbuppa Primjira P PP Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20100320 Pt 4

The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.060 (3) Å]. In the crystal structure, mol-ecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H⋯π. ...[more]

PMID: 21580519

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