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[(Z)-Ethyl N-isopropyl-thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

ABSTRACT: The Au(I) atom in the title compound, [Au(C(6)H(12)NOS)(C(18)H(33)P)], is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P angle = 173.44?(5)°], with the distortion due in part to a close intra-molecular Au?O contact [3.023?(4)?Å]. The N-bound isopropyl group is disordered over two orientations in a 0.618?(15):0.382?(15) ratio.

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2979388 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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[(Z)-Ethyl N-isopropyl-thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Tadbuppa Primjira P PP Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20100508 Pt 6

The Au(I) atom in the title compound, [Au(C(6)H(12)NOS)(C(18)H(33)P)], is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P angle = 173.44 (5)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.023 (4) Å]. The N-bound isopropyl group is disordered over two orientations in a 0.618 (15):0.382 (15) ratio. ...[more]

PMID: 21579274

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