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Bis(4-amino-benzene-sulfonato-?O)bis-(propane-1,3-diamine-?N,N')copper(II) dihydrate.

ABSTRACT: In the title compound, [Cu(C(3)H(10)N(2))(2)(C(6)H(6)NO(3)S)(2)]·2H(2)O, the Cu(II) atom lies on an inversion center and is hexa-coordinated by four N atoms from two 1,3-diamino-propane ligands and two O atoms from two 4-amino-benzene-sulfonate ligands in a trans arrangement, displaying a distorted and axially elongated octa-hedral coordination geometry, with the O atoms at the axial positions. A three-dimensional network is formed in the crystal structure through O-H?O, N-H?O and N-H?N hydrogen bonds.

SUBMITTER: Zhang KJ 

PROVIDER: S-EPMC2972104 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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Bis(4-amino-benzene-sulfonato-κO)bis-(propane-1,3-diamine-κN,N')copper(II) dihydrate.

Zhang Ke-Juan KJ   Meng Xiang-Gao XG   Li Xiu-Ling XL  

Acta crystallographica. Section E, Structure reports online 20091125 Pt 12

In the title compound, [Cu(C(3)H(10)N(2))(2)(C(6)H(6)NO(3)S)(2)]·2H(2)O, the Cu(II) atom lies on an inversion center and is hexa-coordinated by four N atoms from two 1,3-diamino-propane ligands and two O atoms from two 4-amino-benzene-sulfonate ligands in a trans arrangement, displaying a distorted and axially elongated octa-hedral coordination geometry, with the O atoms at the axial positions. A three-dimensional network is formed in the crystal structure through O-H⋯O, N-H⋯O and N-H⋯N hydrogen  ...[more]

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