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Hexaaqua-magnesium(II) bis-(d-camphor-10-sulfonate).

ABSTRACT: The structure of the title complex, [Mg(H(2)O)(6)](C(10)H(15)O(4)S)(2), consists of regular octa-hedral [Mg(H(2)O)(6)](2+) cations and d-camphor-10-sulfonate anions. A three-dimensional supra-molecular architecture is formed via hydrogen-bond inter-actions [O-H?O = 2.723?(2)-2.833?(2)?Å] to give alternating layers of [Mg(H(2)O)(6)](2+) cations and d-camphor-10-sulfonate anions. The title compound is isomorphous with the zinc, copper, cadmium and nickel analogues.

SUBMITTER: Jeremic D 

PROVIDER: S-EPMC2961654 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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Hexaaqua-magnesium(II) bis-(d-camphor-10-sulfonate).

Jeremić Dejan D   Kaluderović Goran N GN   Brčeski Ilija I   Gómez-Ruiz Santiago S   Andelković Katarina K KK  

Acta crystallographica. Section E, Structure reports online 20080621 Pt 7

The structure of the title complex, [Mg(H(2)O)(6)](C(10)H(15)O(4)S)(2), consists of regular octa-hedral [Mg(H(2)O)(6)](2+) cations and d-camphor-10-sulfonate anions. A three-dimensional supra-molecular architecture is formed via hydrogen-bond inter-actions [O-H⋯O = 2.723 (2)-2.833 (2) Å] to give alternating layers of [Mg(H(2)O)(6)](2+) cations and d-camphor-10-sulfonate anions. The title compound is isomorphous with the zinc, copper, cadmium and nickel analogues. ...[more]

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