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(R,R)-N,N'-Bis(ferrocenylmeth-yl)cyclo-hexane-1,2-diamine.

ABSTRACT: In the structure of the title compound, [Fe(2)(C(5)H(5))(2)(C(18)H(24)N(2))], the cyclo-hexane ring has a chair configuration and the two ferrocenemethyl-amino groups are bonded to it equatorially, as expected. The configuration of the two ferrocence nuclei may be due to intra-molecular N-H?N hydrogen bonding involving the two NH groups.

SUBMITTER: Wang Y

PROVIDER: S-EPMC2977100 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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(R,R)-N,N'-Bis(ferrocenylmeth-yl)cyclo-hexane-1,2-diamine.

Wang Yingchun Y

Acta crystallographica. Section E, Structure reports online 20090704 Pt 8

In the structure of the title compound, [Fe(2)(C(5)H(5))(2)(C(18)H(24)N(2))], the cyclo-hexane ring has a chair configuration and the two ferrocenemethyl-amino groups are bonded to it equatorially, as expected. The configuration of the two ferrocence nuclei may be due to intra-molecular N-H⋯N hydrogen bonding involving the two NH groups. ...[more]

PMID: 21583339

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