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Bis[N,N'-bis-[(1H-pyrrol-2-yl)methyl-ene]cyclo-hexane-1,2-diamine]titanium(IV) tetra-hydro-furan solvate.

ABSTRACT: In the title compound, [Ti(C(16)H(18)N(4))(2)]·C(4)H(8)O, the Ti(IV) ion is chelated by two Schiff base dianions with a TiN(8) distorted square-anti-prismatic coordination geometry. The two cyclo-hexane rings assume the typical chair conformation. No hydrogen bonding is observed in the crystal structure.

SUBMITTER: Zhang XQ 

PROVIDER: S-EPMC2960382 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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Bis[N,N'-bis-[(1H-pyrrol-2-yl)methyl-ene]cyclo-hexane-1,2-diamine]titanium(IV) tetra-hydro-furan solvate.

Zhang Xue-Qin XQ   Xu Bin B   Li Ya-Hong YH   Li Wu W  

Acta crystallographica. Section E, Structure reports online 20080130 Pt 2

In the title compound, [Ti(C(16)H(18)N(4))(2)]·C(4)H(8)O, the Ti(IV) ion is chelated by two Schiff base dianions with a TiN(8) distorted square-anti-prismatic coordination geometry. The two cyclo-hexane rings assume the typical chair conformation. No hydrogen bonding is observed in the crystal structure. ...[more]

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