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Tris[4,4,4-trifluoro-1-(2-thien-yl)butane-1,3-dionato]aluminium(III)-tris-[4,4,4-trifluoro-1-(2-thien-yl)butane-1,3-dion-ato]iron(III) (3/1).

ABSTRACT: In the title compound, [Al(C(8)H(4)F(3)O(2)S)(3)](3)[Fe(C(8)H(4)F(3)O(2)S)(3)], the metal centre is statistically occupied by Al(III) and Fe(III) cations in a 3:1 ratio. The metal centre is within an octa-hedral O(6) donor set defined by three chelating substituted acetoacetonate anions. The ligands are arranged around the periphery of the mol-ecule with a mer geometry of the S atoms.

SUBMITTER: Schultz M

PROVIDER: S-EPMC2977190 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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Tris[4,4,4-trifluoro-1-(2-thien-yl)butane-1,3-dionato]aluminium(III)-tris-[4,4,4-trifluoro-1-(2-thien-yl)butane-1,3-dion-ato]iron(III) (3/1).

Schultz Madeleine M Roa Elnor C EC

Acta crystallographica. Section E, Structure reports online 20090725 Pt 8

In the title compound, [Al(C(8)H(4)F(3)O(2)S)(3)](3)[Fe(C(8)H(4)F(3)O(2)S)(3)], the metal centre is statistically occupied by Al(III) and Fe(III) cations in a 3:1 ratio. The metal centre is within an octa-hedral O(6) donor set defined by three chelating substituted acetoacetonate anions. The ligands are arranged around the periphery of the mol-ecule with a mer geometry of the S atoms. ...[more]

PMID: 21583424

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