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Bis{1-[4-(benz-yloxy)phen-yl]-4,4,4-tri-fluoro-butane-1,3-dionato(1-)}dipyri-dine-cobalt(II).

ABSTRACT: In the title compound, [Co(C(17)H(12)F(3)O(3))(2)(C(5)H(5)N)(2)], the Co(II) ion is situated on a twofold rotation axis, coordinated by four O atoms from two 1-[4-(benz-yloxy)phen-yl]-4,4,4-trifluoro-butane-1,3-dionate(1-) (L) ligands and two N atoms from two pyridine ligands in a distorted octa-hedral geometry. The two pyridine rings form a dihedral angle of 84.63?(7)°. The two benzene rings in L are twisted at 58.83?(5)°. Weak inter-molecular C-H?F hydrogen bonds consolidate the crystal packing.

SUBMITTER: Fan L

PROVIDER: S-EPMC3247528 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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Bis{1-[4-(benz-yloxy)phen-yl]-4,4,4-tri-fluoro-butane-1,3-dionato(1-)}dipyri-dine-cobalt(II).

Fan Ling L Chen Yongzhou Y Wei Xianhong X Yin Guodong G

Acta crystallographica. Section E, Structure reports online 20111029 Pt 11

In the title compound, [Co(C(17)H(12)F(3)O(3))(2)(C(5)H(5)N)(2)], the Co(II) ion is situated on a twofold rotation axis, coordinated by four O atoms from two 1-[4-(benz-yloxy)phen-yl]-4,4,4-trifluoro-butane-1,3-dionate(1-) (L) ligands and two N atoms from two pyridine ligands in a distorted octa-hedral geometry. The two pyridine rings form a dihedral angle of 84.63 (7)°. The two benzene rings in L are twisted at 58.83 (5)°. Weak inter-molecular C-H⋯F hydrogen bonds consolidate the crystal packin ...[more]

PMID: 22219833

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