Unknown

Dataset Information

0

(1-Ferrocenyl-4,4,4-trifluoro-butane-1,3-dionato-?O,O)bis-(triphenyl-phosphane)copper(I).

ABSTRACT: In the title mononuclear coordination complex, [CuFe(C(5)H(5))(C(9)H(5)F(3)O(2))(C(18)H(15)P)(2)], the Cu(I) ion is coordinated by the chelating ?-diketonate 1-ferrocenyl-4,4,4-trifluoro-butane-1,3-dione ligand through two O atoms and the two datively bonded triphenyl-phosphane ligands resulting in a distorted tetra-hedral coordination sphere. The Cu(I) ion, together with its chelating butane-1,3-dione group, is mutually coplanar [greatest displacement of an atom from this plane = 0.037?(1)?Å], and the Cu(I) ion lies slightly above [0.013?(1)?Å] the plane. The overall geometry, including the bond distances and angles within the complex, corresponds to those of other reported copper(I) ?-diketon-ates featuring organic groups at the ?-diketonate ligand.

SUBMITTER: Ruffer T 

PROVIDER: S-EPMC3051674 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

(1-Ferrocenyl-4,4,4-trifluoro-butane-1,3-dionato-κO,O)bis-(triphenyl-phosphane)copper(I).

Rüffer Tobias T   Joubert Chris C CC   Buitendach Blenerhassit E BE   Swarts Jannie C JC   Jakob Alexander A   Lang Heinrich H  

Acta crystallographica. Section E, Structure reports online 20110122 Pt 2

In the title mononuclear coordination complex, [CuFe(C(5)H(5))(C(9)H(5)F(3)O(2))(C(18)H(15)P)(2)], the Cu(I) ion is coordinated by the chelating β-diketonate 1-ferrocenyl-4,4,4-trifluoro-butane-1,3-dione ligand through two O atoms and the two datively bonded triphenyl-phosphane ligands resulting in a distorted tetra-hedral coordination sphere. The Cu(I) ion, together with its chelating butane-1,3-dione group, is mutually coplanar [greatest displacement of an atom from this plane = 0.037 (1) Å],  ...[more]

Similar Datasets

Unknown Potassium bis-(1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato)bis-(4,4,4-trifluoro-1-phenyl-butane-1,3-dionato)europate(III).
| S-EPMC3006768 | biostudies-literature
Unknown Tris[4,4,4-trifluoro-1-(2-thien-yl)butane-1,3-dionato]aluminium(III)-tris-[4,4,4-trifluoro-1-(2-thien-yl)butane-1,3-dion-ato]iron(III) (3/1).
| S-EPMC2977190 | biostudies-literature
Unknown (N,N-Diethyl-nicotinamide-?N)bis-[4,4,4-trifluoro-1-(thien-2-yl)butane-1,3-dionato-?O,O']copper(II).
| S-EPMC3120436 | biostudies-other
Unknown Bis(pyridine-?N)bis-[4,4,4-trifluoro-1-(4-fluoro-phen-yl)butane-1,3-dionato-?O,O']cobalt(II).
| S-EPMC2960175 | biostudies-other
Unknown Bis{1-[4-(benz-yloxy)phen-yl]-4,4,4-tri-fluoro-butane-1,3-dionato(1-)}dipyri-dine-cobalt(II).
| S-EPMC3247528 | biostudies-literature
Unknown Propyl-ammonium 4,4,4-trifluoro-1-(naphthalen-2-yl)butane-1,3-dionate.
| S-EPMC3239027 | biostudies-literature
Unknown Poly[?2-aqua-?4-[1-(4-chloro-phen-yl)-4,4,4-tri-fluoro-butane-1,3-dionato]-potassium].
| S-EPMC3772444 | biostudies-literature
Unknown catena-Poly[[(triphenyl-phosphane-?P)copper(I)]-di-?-bromido-[(triphenyl-phos-phane-?P)copper(I)]-?-1,3-bis(pyridin-4-yl)-propane-?N:N'].
| S-EPMC3297220 | biostudies-literature
Unknown catena-Poly[[(triphenyl-phosphane)copper(I)]-di-?-iodido-[(triphenyl-phosphane)copper(I)]-?-{1,2-bis-[1-(pyridin-4-yl)ethyl-idene]hydrazine}].
| S-EPMC3201507 | biostudies-literature
Unknown Chlorido(1H-imidazole-?N)bis-(triphenyl-phosphane-?P)copper(I).
| S-EPMC3120300 | biostudies-literature