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(1-Ferrocenyl-4,4,4-trifluoro-butane-1,3-dionato-?O,O)bis-(triphenyl-phosphane)copper(I).

ABSTRACT: In the title mononuclear coordination complex, [CuFe(C(5)H(5))(C(9)H(5)F(3)O(2))(C(18)H(15)P)(2)], the Cu(I) ion is coordinated by the chelating ?-diketonate 1-ferrocenyl-4,4,4-trifluoro-butane-1,3-dione ligand through two O atoms and the two datively bonded triphenyl-phosphane ligands resulting in a distorted tetra-hedral coordination sphere. The Cu(I) ion, together with its chelating butane-1,3-dione group, is mutually coplanar [greatest displacement of an atom from this plane = 0.037?(1)?Å], and the Cu(I) ion lies slightly above [0.013?(1)?Å] the plane. The overall geometry, including the bond distances and angles within the complex, corresponds to those of other reported copper(I) ?-diketon-ates featuring organic groups at the ?-diketonate ligand.

SUBMITTER: Ruffer T

PROVIDER: S-EPMC3051674 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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(1-Ferrocenyl-4,4,4-trifluoro-butane-1,3-dionato-κO,O)bis-(triphenyl-phosphane)copper(I).

Rüffer Tobias T Joubert Chris C CC Buitendach Blenerhassit E BE Swarts Jannie C JC Jakob Alexander A Lang Heinrich H

Acta crystallographica. Section E, Structure reports online 20110122 Pt 2

In the title mononuclear coordination complex, [CuFe(C(5)H(5))(C(9)H(5)F(3)O(2))(C(18)H(15)P)(2)], the Cu(I) ion is coordinated by the chelating β-diketonate 1-ferrocenyl-4,4,4-trifluoro-butane-1,3-dione ligand through two O atoms and the two datively bonded triphenyl-phosphane ligands resulting in a distorted tetra-hedral coordination sphere. The Cu(I) ion, together with its chelating butane-1,3-dione group, is mutually coplanar [greatest displacement of an atom from this plane = 0.037 (1) Å], ...[more]

PMID: 21522889

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