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Triphenyl-methyl benzoate.


ABSTRACT: The title compound, C(26)H(20)O(2), has long been known, but was not structurally characterized until now. It adopts the Z conformation and the atoms comprising the ester linkage are essentially coplanar (r.m.s. deviation of 0.0234?Å). The acyl C-O bond length of 1.470?(2)?Å falls within the normal range seen for esters of tertiary alcohols and is below the value of 1.496?Å found in tri-tert-butyl-methyl 4-nitro-benzoate.

SUBMITTER: Sykora RE 

PROVIDER: S-EPMC2977206 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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Triphenyl-methyl benzoate.

Sykora Richard E RE   McDonald Lane L   Spyridis Greg T GT  

Acta crystallographica. Section E, Structure reports online 20090729 Pt 8


The title compound, C(26)H(20)O(2), has long been known, but was not structurally characterized until now. It adopts the Z conformation and the atoms comprising the ester linkage are essentially coplanar (r.m.s. deviation of 0.0234 Å). The acyl C-O bond length of 1.470 (2) Å falls within the normal range seen for esters of tertiary alcohols and is below the value of 1.496 Å found in tri-tert-butyl-methyl 4-nitro-benzoate. ...[more]

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