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2-(3-Pyridinio)benzimidazolium penta-chloridobismuthate(III) monohydrate.

ABSTRACT: In the title compound, (C(12)H(11)N(3))[BiCl(5)]·H(2)O, the Bi(III) atom is coordinated by five chloride anions in a distorted square-pyramidal geometry. The planar imidazole ring system [maximum deviation = 0.012?(3)?Å] is oriented at a dihedral angle of 6.08?(5)° with respect to the protonated pyridine ring. An O-H?Cl inter-action links the water mol-ecule to the dianion. In the crystal structure, inter-molecular O-H?Cl, N-H?O and N-H?Cl inter-actions link the mol-ecules into a three-dimensional network.

SUBMITTER: Cui LJ 

PROVIDER: S-EPMC2977254 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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2-(3-Pyridinio)benzimidazolium penta-chloridobismuthate(III) monohydrate.

Cui Li-Jing LJ   Xu Hai-Jun HJ   Pang Yi-Jie YJ  

Acta crystallographica. Section E, Structure reports online 20090701 Pt 8

In the title compound, (C(12)H(11)N(3))[BiCl(5)]·H(2)O, the Bi(III) atom is coordinated by five chloride anions in a distorted square-pyramidal geometry. The planar imidazole ring system [maximum deviation = 0.012 (3) Å] is oriented at a dihedral angle of 6.08 (5)° with respect to the protonated pyridine ring. An O-H⋯Cl inter-action links the water mol-ecule to the dianion. In the crystal structure, inter-molecular O-H⋯Cl, N-H⋯O and N-H⋯Cl inter-actions link the mol-ecules into a three-dimension  ...[more]

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