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2-(3-Pyridinio)benzimidazolium penta-chloridoanti-monate(III) monohydrate.

ABSTRACT: In the title compound, (C(12)H(11)N(3))[SbCl(5)]·H(2)O, the Sb(III) centre is surrounded by five Cl atoms and displays a distorted square-pyramidal coordination geometry. The dihedral angle formed by the plane of the imidazole ring system with the pyridine ring is 4.380?(15)°. The crystal structure is stabilized by N-H?Cl, O-H?Cl and N-H?O hydrogen bonds, forming a three-dimensional network.

SUBMITTER: Cui LJ

PROVIDER: S-EPMC2969637 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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2-(3-Pyridinio)benzimidazolium penta-chloridoanti-monate(III) monohydrate.

Cui Li-Jing LJ Xu Hai-Jun HJ Pan Ke-Ji KJ

Acta crystallographica. Section E, Structure reports online 20090523 Pt 6

In the title compound, (C(12)H(11)N(3))[SbCl(5)]·H(2)O, the Sb(III) centre is surrounded by five Cl atoms and displays a distorted square-pyramidal coordination geometry. The dihedral angle formed by the plane of the imidazole ring system with the pyridine ring is 4.380 (15)°. The crystal structure is stabilized by N-H⋯Cl, O-H⋯Cl and N-H⋯O hydrogen bonds, forming a three-dimensional network. ...[more]

PMID: 21583035

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