Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Diisonicotinium penta-chloridoanti-monate(III) monohydrate.

ABSTRACT: In the title compound, (C(6)H(6)NO(2))(2)[SbCl(5)]·H(2)O, the Sb(III) atom exhibits a distorted square-pyramidal coordination geometry. The crystal structure is stabilized by inter-molecular N-H⋯Cl, N-H⋯O, O-H⋯Cl and O-H⋯O hydrogen bonds, forming an extended three-dimensional network.

SUBMITTER: Chen LZ

PROVIDER: S-EPMC2969829 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Diisonicotinium penta-chloridoanti-monate(III) monohydrate.

Chen Li-Zhuang LZ

Acta crystallographica. Section E, Structure reports online 20090523 Pt 6

In the title compound, (C(6)H(6)NO(2))(2)[SbCl(5)]·H(2)O, the Sb(III) atom exhibits a distorted square-pyramidal coordination geometry. The crystal structure is stabilized by inter-molecular N-H⋯Cl, N-H⋯O, O-H⋯Cl and O-H⋯O hydrogen bonds, forming an extended three-dimensional network. ...[more]

PMID: 21583042

Similar Datasets

N-Methyl-piperazinediium penta-chloridoanti-monate(III) monohydrate.

Project description:The asymmetric unit of the title compound, (C(5)H(14)N(2))[SbCl(5)]·H(2)O, consists of an N-methyl-piperazinediium cation, a penta-chloridoanti-monate anion with the Sb(III) ion in a slightly distorted square-pyramidal coordination environment, and one solvent water mol-ecule. The crystal structure is stabilized by inter-molecular N-H⋯Cl, O-H⋯Cl and N-H⋯O hydrogen bonds.

| S-EPMC2915089 | biostudies-literature

2-(3-Pyridinio)benzimidazolium penta-chloridoanti-monate(III) monohydrate.

Project description:In the title compound, (C(12)H(11)N(3))[SbCl(5)]·H(2)O, the Sb(III) centre is surrounded by five Cl atoms and displays a distorted square-pyramidal coordination geometry. The dihedral angle formed by the plane of the imidazole ring system with the pyridine ring is 4.380?(15)°. The crystal structure is stabilized by N-H?Cl, O-H?Cl and N-H?O hydrogen bonds, forming a three-dimensional network.

| S-EPMC2969637 | biostudies-literature

Dimorpholinium penta-chloridoanti-monate(III).

Project description:The asymmetric unit of the title compound, (C(4)H(10)NO)(2)[SbCl(5)], consists of two morpholinium cations in chair conformations, and a penta-chloridoanti-monate dianion with the Sb(III) ion in a slightly distorted square-pyramidal coordination environment. The morpholinium cations are connected to each other by N-H⋯O hydrogen bonds, and they link the chloride anions and the anti-monate SbCl(3) group via N-H⋯Cl contacts.

| S-EPMC2969790 | biostudies-literature

Doxofyllinium tetra-chloridoanti-monate(III) monohydrate.

Project description:The title compound, (C(11)H(14)N(4)O(4))[SbCl(4)]·H(2)O, comprises a protonated doxofyllinium cation [7-(1,3-dioxolan-2-ylmeth-yl)-1,3-dimethyl-2,6-dioxo-3,7-dihydro-1H-purin-9-ium], an [SbCl(4)](-) anion and a water mol-ecule linked by N-H⋯O and O-H⋯Cl hydrogen bonds: the [SbCl(4)](-) anions form centrosymmetric dimers via weak Sb⋯Cl inter-actions [Sb⋯Cl = 3.1159 (9) Å]. The geometrical arrangement in the crystal structure is characterized by slipped π-π stacking of the parallel purine ring systems, with an inter-planar separation of 3.32 Å.

| S-EPMC2915103 | biostudies-literature

Tris(4-methyl-anilinium) penta-chlorido-anti-monate(III) chloride monohydrate.

Project description:The title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl·H(2)O, consists of 4-methyl-anilinium cations, Cl(-) and [SbCl(5)](2-) anions and water mol-ecules. The five Cl atoms bound to Sb [Sb-Cl = 2.4043?(9)-2.6262?(11)?Å] form a square-pyramidal coordination environment. In addition, two [SbCl(5)](2-) anions related by an inversion center are joined by Sb?Cl inter-actions [Sb?Cl = 3.7273?(14)?Å] into an [Sb(2)Cl(10)](4-) dimer with two bridging Cl atoms. The anions, water mol-ecules and ammonium groups of the cations are linked by N-H?Cl, N-H?O and O-H?Cl hydrogen bonds, forming layers parallel to the ac plane. The benzene rings of the 4-methyl-anilinium cations are packed between these layers.

| S-EPMC3343837 | biostudies-other

(R)-2-Methyl-piperazine-1,4-diium tetra-chloridoanti-monate(III) chloride.

Project description:In the complex anion of the title compound, (C(5)H(14)N(2))[SbCl(4)]Cl, the Sb atom is tetra-coordinate within a saw-horse configuration. The cation adopts a chair conformation. The crystal structure is stabilized by inter-molecular N-H?Cl hydrogen bonds.

| S-EPMC3011473 | biostudies-literature

Bis(2-methyl-piperidinium) penta-chlorido-anti-monate(III).

Project description:The asymmetric unit of the title compound, (C(6)H(14)N)(2)[SbCl(5)], contains one cation and half of the anion on a special position (specifically, the Sb(III) ion and three chloride anions are situated on a mirror plane). In the [SbCl(5)](2-) unit, the Sb(III) ion is coordinated by five chloride anions [Sb-Cl = 2.3721?(11)-2.6656?(12)?Å] in a distorted square-pyramidal geometry. However, one chloride anion from a neighbouring [SbCl(5)](2-) unit provides a short Sb?Cl contact of 3.3600?(12)?Å and completes the Sb coordination environment up to an elongated octa-hedron. In the crystal, N-H?Cl hydrogen bonds link cations and anions into columns propagating along [100].

| S-EPMC3344392 | biostudies-literature

Tris(3-methyl-anilinium) penta-chlorido-anti-monate(III) chloride.

Project description:In the title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl, the Sb(III) cation is coordinated by five Cl(-) anions in a distorted square-pyramidal geometry, in which the longest Sb-Cl distance of 3.0319?(14)?Å indicates a weak coordination bond. In the crystal, the 3-methyl-anilinium cations link with the complex antimonate anions and Cl(-) anions via N-H?Cl hydrogen bonds.

| S-EPMC3238716 | biostudies-literature

2-(3-Pyridinio)benzimidazolium penta-chloridobismuthate(III) monohydrate.

Project description:In the title compound, (C(12)H(11)N(3))[BiCl(5)]·H(2)O, the Bi(III) atom is coordinated by five chloride anions in a distorted square-pyramidal geometry. The planar imidazole ring system [maximum deviation = 0.012?(3)?Å] is oriented at a dihedral angle of 6.08?(5)° with respect to the protonated pyridine ring. An O-H?Cl inter-action links the water mol-ecule to the dianion. In the crystal structure, inter-molecular O-H?Cl, N-H?O and N-H?Cl inter-actions link the mol-ecules into a three-dimensional network.

| S-EPMC2977254 | biostudies-literature

Aqua-bis-(4-methyl-benzene-sulfonato-?O)(?(5)-penta-methyl-cyclo-penta-dien-yl)rhodium(III) monohydrate.

Project description:The title half-sandwich rhodium(III) complex, [Rh(C10H15)(C7H7O3S)2(H2O)]·H2O, consists of a ?-bonded penta-methyl-cyclo-penta-dienyl group, two ?-bonded tosyl-ate groups and an aqua ligand. The structure displays both inter- and intra-molecular O-H?O hydrogen bonding. The inter-molecular hydrogen bonding results in an extended helical chain along a 21 screw axis parallel to c, due to hydrogen bonding from the coordinating water ligand to the lattice water mol-ecule and then to a sulfonate O atom of a different asymmetric unit.

| S-EPMC3647804 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data