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3-(1-Adamantylamino)-3-methyl-1-phenyl-quinoline-2,4(1H,3H)-dione.

ABSTRACT: The structure of the title compound, C(26)H(28)N(2)O(2), contains essentially planar quinoline and benzene rings, the maximum deviations from the best plane being 0.086?(2) and 0.0056?(19)?Å, respectively; the dihedral angle between the rings is 82.87?(4)°. The adamantane cage consists of three fused cyclo-hexane rings in classical chair conformations, with C-C-C angles in the range 107.85?(15)-111.35?(15)°. Enanti-omers are linked alternately into chains along the c axis via short N-H?O inter-actions and further C-H?? inter-actions stabilize pairs of enanti-omers, forming a two-dimensional network.

SUBMITTER: Mahmoodi N

PROVIDER: S-EPMC2977340 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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3-(1-Adamantylamino)-3-methyl-1-phenyl-quinoline-2,4(1H,3H)-dione.

Mahmoodi Niusha N Nečas Marek M Vícha Robert R

Acta crystallographica. Section E, Structure reports online 20090715 Pt 8

The structure of the title compound, C(26)H(28)N(2)O(2), contains essentially planar quinoline and benzene rings, the maximum deviations from the best plane being 0.086 (2) and 0.0056 (19) Å, respectively; the dihedral angle between the rings is 82.87 (4)°. The adamantane cage consists of three fused cyclo-hexane rings in classical chair conformations, with C-C-C angles in the range 107.85 (15)-111.35 (15)°. Enanti-omers are linked alternately into chains along the c axis via short N-H⋯O inter-a ...[more]

PMID: 21583562

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