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Poly[bis-(N,N-dimethyl-formamide)(?-formato)(?(5)-4-oxidoisophthalato)dizinc(II)].

ABSTRACT: The title compound, [Zn(2)(CHO(2))(C(8)H(3)O(5))(C(3)H(7)NO)(2)](n), is a three-dimensional metal-organic framework, of which two independent Zn(II) atoms (denoted Zn1 and Zn2) are linked by both 4-oxidoisophthalate and formate bridging ligands. The 4-oxidoisophthalate ligands link two Zn1-type and three Zn2-type atoms, forming a corrugated sheet roughly parallel to the ac plane. The formate ions join two neighboring sheets along the b axis, forming a three-dimensional network. Two independent dimethylformamide ligands are coordinated to separate Zn(II) atoms and fill the voids provided by the framework. Both types of Zn(II) atoms have a distorted trigonal-bipyramidal coordination geometry.

SUBMITTER: Jhon YH

PROVIDER: S-EPMC2977363 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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Poly[bis-(N,N-dimethyl-formamide)(μ-formato)(μ(5)-4-oxidoisophthalato)dizinc(II)].

Jhon Young Ho YH Kim Jaheon J

Acta crystallographica. Section E, Structure reports online 20090725 Pt 8

The title compound, [Zn(2)(CHO(2))(C(8)H(3)O(5))(C(3)H(7)NO)(2)](n), is a three-dimensional metal-organic framework, of which two independent Zn(II) atoms (denoted Zn1 and Zn2) are linked by both 4-oxidoisophthalate and formate bridging ligands. The 4-oxidoisophthalate ligands link two Zn1-type and three Zn2-type atoms, forming a corrugated sheet roughly parallel to the ac plane. The formate ions join two neighboring sheets along the b axis, forming a three-dimensional network. Two independent d ...[more]

PMID: 21583431

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