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Poly[dimethyl-ammonium [tris-(?(2)-formato-?O:O')cadmate(II)]].

ABSTRACT: In the coordination polymer, {(C(2)H(8)N)[Cd(CHO(2))(3)]}(n), the Cd(II) atom lies on a special position of site symmetry in an octa-hedron of O atoms. The formate unit bridges the metal atoms, generating a three-dimensional polyanionic framework. The disordered cations occupy the cavities within the framework, and are N-H?O hydrogen-bonded to the framework.

SUBMITTER: Gao S

PROVIDER: S-EPMC3011599 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Poly[dimethyl-ammonium [tris-(μ(2)-formato-κO:O')cadmate(II)]].

Gao Shan S Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20101120 Pt 12

In the coordination polymer, {(C(2)H(8)N)[Cd(CHO(2))(3)]}(n), the Cd(II) atom lies on a special position of site symmetry in an octa-hedron of O atoms. The formate unit bridges the metal atoms, generating a three-dimensional polyanionic framework. The disordered cations occupy the cavities within the framework, and are N-H⋯O hydrogen-bonded to the framework. ...[more]

PMID: 21589281

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