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Dibromidotris(dimethyl-amine)magnesium(II).

ABSTRACT: The Mg centre in the title compound, [MgBr(2)(C(2)H(7)N)(3)], is penta-coordinated in a trigonal-bipyramidal mode with the two Br atoms in axial positions and the N atoms of the dimethyl-amine ligands in equatorial positions. The Mg(II) centre is located on a crystallographic twofold rotation axis. The crystal structure is stabilized by N-H?Br hydrogen bonds. The N atom and H atoms of one dimethylamine ligand are disordered over two equally occupied positions.

SUBMITTER: Vitze H

PROVIDER: S-EPMC2977434 | biostudies-literature | 2009

REPOSITORIES: biostudies-literature

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Dibromidotris(dimethyl-amine)magnesium(II).

Vitze Hannes H Lerner Hans-Wolfram HW Bolte Michael M

Acta crystallographica. Section E, Structure reports online 20090708 Pt 8

The Mg centre in the title compound, [MgBr(2)(C(2)H(7)N)(3)], is penta-coordinated in a trigonal-bipyramidal mode with the two Br atoms in axial positions and the N atoms of the dimethyl-amine ligands in equatorial positions. The Mg(II) centre is located on a crystallographic twofold rotation axis. The crystal structure is stabilized by N-H⋯Br hydrogen bonds. The N atom and H atoms of one dimethylamine ligand are disordered over two equally occupied positions. ...[more]

PMID: 21583351

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