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Tetra-aqua-bis[4-(4-pyrid-yl)pyrimidine-2-sulfonato]copper(II) dihydrate.

ABSTRACT: In the title complex, [Cu(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)]·2H(2)O, the Cu(II) atom lies on an inversion centre and is coordinated by four water mol-ecules in equatorial positions and two N atoms from two 4-(4-pyrid-yl)pyrimidine-2-sulfonate ligands in apical positions. The asymmetric unit contains half of the complex and one free water mol-ecule. The water mol-ecules, including the uncoordinated water mol-ecules, and sulfonate O atoms are involved in O-H?O and O-H?N hydrogen-bonding inter-actions.

SUBMITTER: Li L 

PROVIDER: S-EPMC2977545 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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Tetra-aqua-bis[4-(4-pyrid-yl)pyrimidine-2-sulfonato]copper(II) dihydrate.

Li Lei L   Xu Gang G   Zhu Hai-Bin HB  

Acta crystallographica. Section E, Structure reports online 20090402 Pt 5

In the title complex, [Cu(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)]·2H(2)O, the Cu(II) atom lies on an inversion centre and is coordinated by four water mol-ecules in equatorial positions and two N atoms from two 4-(4-pyrid-yl)pyrimidine-2-sulfonate ligands in apical positions. The asymmetric unit contains half of the complex and one free water mol-ecule. The water mol-ecules, including the uncoordinated water mol-ecules, and sulfonate O atoms are involved in O-H⋯O and O-H⋯N hydrogen-bonding inter-action  ...[more]

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