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Bis(1,3-dibenzyl-imidazolium) μ-oxido-bis-[trichloridoferrate(III)].

ABSTRACT: In the title compound (C(17)H(17)N(2))(2)[Fe(2)Cl(6)O], obtained from the solid-state reaction of FeCl(2) and N,N'-dibenzyl-imidazolium chloride, the complex anion has approximate D(3d) symmetry with crystallographically imposed inversion symmetry coincident with the bridging μ-O atom. The stereochemistry about each FeCl(3)O centre is distorted tetra-hedral [Fe-Cl = 2.2176 (5)-2.2427 (5) Å and Fe-O = 1.7545 (2) Å]. The Cl atoms are involved in weak anion-cation C-H⋯Cl inter-actions, giving a network structure.

SUBMITTER: Mutambi EM

PROVIDER: S-EPMC3006938 | biostudies-literature |

REPOSITORIES: biostudies-literature

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catena-Poly[bis(1,3-benzo-thia-zol-3-ium) [[di-chlorido-anti-monate(III)]-di-μ-chlorido-μ-oxido-[chlorido-anti-monate(III)]-μ-chlorido]].

Project description:The title compound, {(C7H6NS)2[Sb2Cl6O]} n , contains two benzo-thia-zolidium cations and one tri-μ-chlorido-tri-chlorido-μ-oxido-di-anti-monate(III) anion. The structure of the inorganic cation may be described as as being built up from two polyhedra, i.e. a square-pyramidal SbCl4O and a distorted octa-hedral SbOCl5 unit, sharing a common face (comprising the O atom and two Cl atoms). The two benzo-thia-zole cations are quasi-planar and subtend a dihedral angle of 19.93 (5)°. The crystal packing can be described by alternating (100) layers and [001] chains of the organic cations and inorganic anions connected through an extensive three-dimensional network of N-H⋯Cl, C-H⋯O and C-H⋯Cl hydrogen bonds. This is consolidated by slipped π-π stacking, with centroid-to-centroid distances between the benzo-thia-zole rings of 3.7111 (18)-3.8452 (16) Å. These inter-actions link the mol-ecules within the layers and also link the layers together and reinforce the cohesion of the ionic structure.

| S-EPMC4770971 | biostudies-literature

1,3-Bis(1-adamant-yl)imidazolium tetra-chloridoferrate(III).

Project description:The crystal structure of the title compound, (C(23)H(33)N(2))[FeCl(4)], consists of 1,3-bis-(1-adamant-yl)imidazolium (BAIM) cations and tetra-hedral tetra-chloridoferrate(III) (TCF) anions. The BAIM cation possesses m symmetry, with the central imidazole ring and four C atoms of each terminal adamantyl group located on a mirror plane. The Fe and two Cl atoms of the TCF anion are also located on the mirror plane. The cyclo-hexane rings of the adamantyl groups adopt normal chair conformations.

| S-EPMC3009177 | biostudies-literature

μ-Oxido-bis-[bis-(phenanthroline-κN,N')(sulfato-κO)iron(III)] octa-hydrate.

Project description:The title complex, [Fe(2)O(SO(4))(2)(C(12)H(8)N(2))(4)]·8H(2)O, contains two unique Fe(III) cations, one oxide anion, four 1,10-phenanthroline (phen) ligands, two coordinated sulfate anions and eight lattice water mol-ecules. Each Fe(III) ion has an approximate octa-hedral geometry, coordinated by four N atoms from two phen mol-ecules, two O atoms from oxide and sulfate anions, respectively. The parallel phen mol-ecules form two-dimensional supermolecules through π-π stacking inter-actions [centroid-centroid distances = 3.684 (3), 3.711 (3), 3.790 (3), 3.847 (3), 3.746 (3), 3.732 (3) and 3.729 (3) Å]. This architecture is further stabilized by O-H⋯O hydrogen bonds involving the lattice water mol-ecules and sulfate O atoms.

| S-EPMC3246986 | biostudies-literature

μ-Oxido-bis-{chlorido[tris-(2-pyridylmeth-yl)amine]chromium(III)} bis(hexafluoridophosphate).

Project description:The title compound, [Cr(2)Cl(2)O(C(18)H(18)N(4))(2)](PF(6))(2), is isostructural with the V(III) analogue. Each Cr(III) atom is chelated by the tetra-dentate tris-(2-pyridylmeth-yl)amine ligand via four N atoms, and further coordinated by one Cl atom and one bridging O atom, giving a slightly distorted octa-hedral coordination geometry. The dinuclear complex is centrosymmetric, with the bridging O atom lying on a centre of inversion.

| S-EPMC2914886 | biostudies-literature

μ-Oxido-bis-{chlorido[tris-(2-pyridylmethyl)amine]manganese(III)} bis-(hexa-fluorido-phosphate).

Project description:In the title compound, [Mn(2)O(C(18)H(18)ClN(4))(2)](PF(6))(2), the Mn atom is chelated by a tetra-dentate ligand via four N atoms, and further bonded to one chloride ion and one bridging oxide, to give a centrosymmetric cation and distorted octa-hedral coordination geometry.

| S-EPMC2915134 | biostudies-literature

Hexa-kis-(dimethyl-formamide-κO)manganese(II) μ-oxido-bis-[trichlorido-ferrate(III)].

Project description:The title compound, [Mn(C(3)H(7)NO)(6)][Fe(2)Cl(6)O], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes with Schiff base ligands using manganese powder and FeCl(3)·6H(2)O as starting materials. In the [Fe(2)OCl(6)](2-) anion, the O atom and the Fe atom occupy positions with site symmetry [Formula: see text] and 3, respectively, resulting in a linear Fe-O-Fe angle and a staggered conformation. The octa-hedrally surrounded cation (site symmetry [Formula: see text]) and the [Fe(2)Cl(6)O](2-) anion are alternately stacked along [001].

| S-EPMC3246982 | biostudies-literature

Bis(?-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)].

Project description:In the title complex, [Sn(2)(C(7)H(7))(4)(C(10)H(8)N(2)O(3))(2)(C(2)H(5)OH)(2)], the Sn(IV) atom is seven-coordinated in a distorted penta-gonal-bipyramidal geometry by three O atoms and one N atom from the pyruvate benzoyl hydrazone ligand, one ethanol O atom and two axial C atoms from trans-benzyl groups, thus forming a dimeric mol-ecule ([Formula: see text] symmetry) via weak Sn-O inter-actions. The C atoms of one phenyl ring and the ethanol mol-ecule are disordered over two sets of sites with site-occupancy factors of 0.57?(5):0.43?(5) and 0.79?(2):0.21?(2), respectively. Intermolecular O-H?O hydrogen bonds stabilize the crystal structure.

| S-EPMC3089280 | biostudies-literature

μ-Oxido-bis-({2,2'-[o-phenylenebis(nitrilo-methylidyne)]diphenolato}iron(III)) methanol monosolvate dihydrate.

Project description:The title complex, [Fe(2)(C(20)H(14)N(2)O(2))(2)O]·CH(4)O·2H(2)O, is composed of μ-oxido-bridged ferric 2,2'-[o-phenylene-bis(nitrilo-methylidyne)]diphenolate (salphen) dimers, one methanol mol-ecule and two H(2)O mol-ecules. Each iron(III) ion, surrounded by two coordinating N and O atoms from the salphen ligand and one bridging O atom, shows a five-coordinate square-pyramidal geometry. One of the two solvent water mol-ecules is disordered over three positions with occupancies of 0.44 (1), 0.37 (1) and 0.19 (1).

| S-EPMC3007942 | biostudies-literature

Hexa-μ(2)-acetato-κO:O'-(azido-κN)bis-(methanol-κO)-μ(3)-oxido-trichromium(III) methanol monosolvate.

Project description:In the crystal structure of the title complex, [Cr(3)(CH(3)CO(2))(6)(N(3))O(CH(3)OH)(2)]·CH(3)OH, the trinuclear core has a central O atom; two methanol mol-ecules and an azide ion are coordinated to the Cr(III) atoms in the core. The three Cr(III) atoms form vertices of a nearly equilateral triangle. Each of the six acetate carboxyl-ate groups bridges a Cr-O-Cr fragment. In the crystal, the molecules inter-act with methanol solvent mol-ecules through O-H⋯O and O-H⋯N hydrogen bonds, forming a two-dimensional hydrogen-bonded network parallel to (100).

| S-EPMC3246918 | biostudies-literature

μ-Oxido-bis-({4,4'-dibromo-2,2'-ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}iron(III)).

Project description:In the title compound, [Fe(2)(C(16)H(12)Br(2)N(2)O(2))(2)O], the complete mol-ecule is generated by twofold symmetry, with the bridging O atom, which links the iron centres, lying on the roatation rotation axis. The Fe(III) ion is chelated by the N,N,O,O-tetra-dentate Schiff base dianion, resulting in an FeN(2)O(3) square-based pyramid, with the two N atoms in the basal plane.

| S-EPMC2914945 | biostudies-literature

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