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(N-sec-Butyl-N-n-propyl-dithio-carbamato-κS,S')triphenyl-tin(IV).

ABSTRACT: The Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(16)NS(2))], is penta-coordinated by two S atoms, derived from an asymmetrically coordinating dithio-carbamate ligand, and three ipso-C atoms. The coordination geometry is inter-mediate between square-pyramidal and trigonal-bipyramidal, with a leaning towards the latter. The presence of close intra-molecular C-H⋯S contacts preclude the S atoms from forming significant inter-molecular inter-actions. Rather, mol-ecules are consolid-ated in the crystal structure by C-H⋯π inter-actions.

SUBMITTER: Awang N

PROVIDER: S-EPMC3007978 | biostudies-literature | 2010 Aug

REPOSITORIES: biostudies-literature

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(N-sec-Butyl-N-n-propyl-dithio-carbamato-κS,S')triphenyl-tin(IV).

Awang Normah N Baba Ibrahim I Yamin Bohari M BM Ng Seik Weng SW Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20100821 Pt 9

The Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(16)NS(2))], is penta-coordinated by two S atoms, derived from an asymmetrically coordinating dithio-carbamate ligand, and three ipso-C atoms. The coordination geometry is inter-mediate between square-pyramidal and trigonal-bipyramidal, with a leaning towards the latter. The presence of close intra-molecular C-H⋯S contacts preclude the S atoms from forming significant inter-molecular inter-actions. Rather, mol-ecules are consolid-ated in t ...[more]

PMID: 21588542

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(N-Butyl-N-phenyl-dithio-carbamato-κS)triphenyl-tin(IV).

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