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Catena-Poly[[diaqua-cadmium(II)]-?-(methyl morpholino dichloro-methylene-diphospho-nato)-?O,O':O''-[tetra-aqua-cadmium(II)]-?-(methyl morpholino dichloro-methyl-enediphospho-nato)-?O:O',O''].

ABSTRACT: The asymmetric unit of the title compound, [Cd(C(6)H(11)Cl(2)NO(6)P(2))(H(2)O)(3)](n), contains two octahedrally coordinated Cd atoms located in special positions, one on a twofold rotation axis and the other on a centre of symmetry. The metal atoms are connected by methyl morpholino dichloro-methyl-enediphospho-nate ligands into chains in the c-axis direction. These chains are further connected by O-H?O hydrogen bonds into a layer-like construction along (100).

SUBMITTER: Jokiniemi J

PROVIDER: S-EPMC2977635 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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catena-Poly[[diaqua-cadmium(II)]-μ-(methyl morpholino dichloro-methylene-diphospho-nato)-κO,O':O''-[tetra-aqua-cadmium(II)]-μ-(methyl morpholino dichloro-methyl-enediphospho-nato)-κO:O',O''].

Jokiniemi Jonna J Vepsäläinen Jouko J Ahlgrén Markku M

Acta crystallographica. Section E, Structure reports online 20090430 Pt 5

The asymmetric unit of the title compound, [Cd(C(6)H(11)Cl(2)NO(6)P(2))(H(2)O)(3)](n), contains two octahedrally coordinated Cd atoms located in special positions, one on a twofold rotation axis and the other on a centre of symmetry. The metal atoms are connected by methyl morpholino dichloro-methyl-enediphospho-nate ligands into chains in the c-axis direction. These chains are further connected by O-H⋯O hydrogen bonds into a layer-like construction along (100). ...[more]

PMID: 21583821

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