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Dicaesium diaqua-bis-(methyl-ene-diphospho-nato-?O,O')cobaltate(II).

ABSTRACT: The asymmetric unit of the title compound, Cs(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], is comprised of one bidentate methyl-enediphospho-nate ligand and one water mol-ecule which are coordinated to the Co(II) atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystallographic inversion center. The caesium ion is octa-hedrally coordinated by six O atoms with Cs-O distances ranging from 3.119?(2) to 3.296?(2)?Å. A three-dimensional network is formed through O-H?O hydrogen bonds.

SUBMITTER: van Merwe K

PROVIDER: S-EPMC3201400 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Dicaesium diaqua-bis-(methyl-ene-diphospho-nato-κO,O')cobaltate(II).

van Merwe Kina K Visser Hendrik G HG Venter Johan A JA

Acta crystallographica. Section E, Structure reports online 20110914 Pt 10

The asymmetric unit of the title compound, Cs(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], is comprised of one bidentate methyl-enediphospho-nate ligand and one water mol-ecule which are coordinated to the Co(II) atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystallographic inversion center. The caesium ion is octa-hedrally coordinated by six O atoms with Cs-O distances ranging from 3.119 (2) to 3.296 (2) Å. A three-dimensional network is formed through O-H⋯O hy ...[more]

PMID: 22065711

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