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1,1-Bis[4-(trifluoro-meth-yl)phen-yl]germetane.


ABSTRACT: The inter-nal C-Ge-C bond angle in the germacyclo-butane ring of the title compound, C(17)H(14)F(6)Ge or [Ge(C(3)H(6))(C(7)H(4)F(3))(2)], is 77.8?(3)°. The -CF(3) groups display rotational disorder [occupancies 0.604?(14):0.396?(14) and 0.410?(6):0.411?(6):0.179?(3)] and the germacyclo-butane ring also shows disorder [occupancies 0.604?(14):0.396?(14)].

SUBMITTER: Huck LA 

PROVIDER: S-EPMC2977636 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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1,1-Bis[4-(trifluoro-meth-yl)phen-yl]germetane.

Huck Lawrence A LA   Potter Gregory D GD   Jenkins Hilary A HA   Britten James F JF   Leigh William J WJ  

Acta crystallographica. Section E, Structure reports online 20090430 Pt 5


The inter-nal C-Ge-C bond angle in the germacyclo-butane ring of the title compound, C(17)H(14)F(6)Ge or [Ge(C(3)H(6))(C(7)H(4)F(3))(2)], is 77.8 (3)°. The -CF(3) groups display rotational disorder [occupancies 0.604 (14):0.396 (14) and 0.410 (6):0.411 (6):0.179 (3)] and the germacyclo-butane ring also shows disorder [occupancies 0.604 (14):0.396 (14)]. ...[more]

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